(bis(N-propylbenzimidazolylmethyl)sulfide)Zn(SCH2CH2Ph)2 | 216979-61-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: (bis(N-propylbenzimidazolylmethyl)sulfide)Zn(SCH2CH2Ph)2
• CAS: 216979-61-2
• 化学式: C₃₈H₄₄N₄S₃Zn
• 分子量: 718.382
• InChiKey: AHAJMVFYOVHFKL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  zinc perchlorate 、 2-苯乙硫醇 、 bis(N-propylbenzimidazolylmethyl)sulfide 在 NaOCH₃ 作用下， 以 甲醇 为溶剂， 以38%的产率得到(bis(N-propylbenzimidazolylmethyl)sulfide)Zn(SCH2CH2Ph)2
  参考文献：
  名称：

  Zinc thiolate complexes with chelating nitrogen ligands

  摘要：

  The thiolates SPh-, SCH2Ph- and SCH2CH2Ph- were combined with polydentate nitrogen donor ligands in monomeric zinc complexes. N-substituted bis(benzimidazolylmethyl)sulfides (R-BIMS) yielded the complexes (R-BIMS)Zn(SR)(2) (1-3) in which the central thioether sulfur does not coordinate. This holds also for the o-hydroxymethyl-thiophenolate complex (4). 2,9-Dimethylphenanthroline (neocuproin, NEO) produced compounds (NEO)Zn(SR)(2) (5). Bis(dimethylpyrazolyI-N-ethyl)amine (PEA) led to (PEA)Zn(SPh)(2) (6) in which only one pyrazole nitrogen and the central amine nitrogen are coordinated. 2-Mercaptomethylpyridine (HMMP) formed the bis-ligand complex (MMP)(2)Zn (7). Six structure determinations have shown that all complexes are characterized by a tetrahedral ZnN2S2 coordination, irrespective of the ring size (5, 6, 8) which is thereby enforced on the chelate ligand, even at the expense of unused ligand donor atoms. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00215-1