diphenylantimony(V) bromide oxide | 102829-02-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenylantimony(V) bromide oxide
• 英文别名: diphenylantimony bromide oxide
• CAS: 102829-02-7
• 化学式: C₂₄H₂₀Br₂O₂Sb₂
• 分子量: 743.73
• InChiKey: IHEJUEPFJYGNAN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.24
• 重原子数：
  30.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  diphenylantimony(V) bromide oxide 在 potassium thioacyanate 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Forster, Glynis E.; Southerington, Gary; Sowerby, D. Bryan, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 64, # 1-4, p. 55 - 62

  摘要：

  DOI：
• 作为产物：
  描述：

  叔丁基过氧化氢 、 diphenylantimony(III) bromide 以 二氯甲烷 为溶剂， 生成 diphenylantimony(V) bromide oxide
  参考文献：
  名称：

  二聚二苯基氧化锑溴化物（Ph 2 SbBrO）2的制备和晶体结构

  摘要：

  溴化二苯基锑（III）和相应的氯化物可被叔丁基氢过氧化物氧化为可溶性产物；X射线晶体学显示了离散的二聚体结构，其包含用于Ph 2 SbBrO的平面Sb 2 O 2环。

  DOI：

  10.1016/0022-328x(85)80254-0

文献信息

• Multiply bridged organodiantimony(V) compounds; crystal structures of [(SbR2)2(μ-O)2(μ -O2AsMe2)2] (R = Ph or p-tolyl) and [(SbR3)2(μ-O)(μ-O2 MR′2)2] (R = Ph, M = P, R′ = Me; R = Ph, M = As, R′ = Me or Ph; R = p-tolyl, M = P, R′ = Me)
  作者：Martin N. Gibbons、D. Bryan Sowerby

  DOI：10.1039/a702244a

  日期：——

  A number of quadruply and triply bridged organodiantimony(V) compounds have been synthesized by reactions of [(SbR 2 BrO) 2 ] (R = Ph or p-tolyl) and [(SbR 3 X) 2 O] (R = Ph or p-tolyl, X = Br or Cl) with Na(O 2 AsMe 2 ), Na(O 2 AsPh 2 ) or Na(O 2 AsMe 2 ). The compounds have been characterised by a range of spectroscopic methods and crystal structures are reported for two quadruply bridged, [(SbPh 2 ) 2 (µ-O) 2 (µ -O 2 AsMe 2 ) 2 ] and [Sb(p-MeC 6 H 4 ) 2 } 2 (µ-O) 2 (µ-O 2 AsMe 2 ) 2 ], and four triply bridged compounds, [(SbPh 3 ) 2 (µ-O)(µ-O 2 PMe 2 ) 2 ], [(SbPh 3 ) 2 (µ-O)(µ-O 2 AsMe 2 ) 2 ], [(SbPh 3 ) 2 (µ-O)(µ-O 2 AsPh 2 ) 2 ] and [Sb(p-MeC 6 H 4 ) 3 } 2 (µ-O)(µ-O 2 PMe 2 ) 2 ]. Related trimethylantimony(V) compounds, i.e. [SbMe 3 (O 2 PMe 2 )} 2 O] and [SbMe 3 (O 2 AsPh 2 )} 2 O], which are highly moisture sensitive, have also been obtained.

  通过[(SbR₂BrO)₂] (R = Ph 或 p-tolyl) 和 [(SbR₃X)₂O] (R = Ph 或 p-tolyl, X = Br 或 Cl) 与 Na(O₂AsMe₂)、Na(O₂AsPh₂) 或 Na(O₂AsMe₂) 的反应，合成了多种四重和三重桥连的组织二锑(V)化合物。这些化合物通过一系列光谱方法进行了表征，并报道了两种四重桥连化合物 [(SbPh₂)₂(µ-O)₂(µ-O₂AsMe₂)₂] 和 [Sb(p-MeC₆H₄)₂}₂(µ-O)₂(µ-O₂AsMe₂)₂]，以及四种三重桥连化合物 [(SbPh₃)₂(µ-O)(µ-O₂PMe₂)₂]、[(SbPh₃)₂(µ-O)(µ-O₂AsMe₂)₂]、[(SbPh₃)₂(µ-O)(µ-O₂AsPh₂)₂] 和 [Sb(p-MeC₆H₄)₃}₂(µ-O)(µ-O₂PMe₂)₂] 的晶体结构。还获得了高度吸湿性的相关三甲基锑(V)化合物，即 [SbMe₃(O₂PMe₂)}₂O] 和 [SbMe₃(O₂AsPh₂)}₂O]。
• A new diphenylantimony oxide containing a planar Sb6O6 ring
  作者：I. Gary Southerington、Michael J. Begley、D. Bryan Sowerby

  DOI：10.1039/c39910001555

  日期：——

  Treatment of diphenylantimony bromide oxide, (Ph2SbBrO)2, with silver oxalate leads to a novel ionic product, containing a planar twelve-membered cyclic antimony–oxygen dication in which two pairs of adjacent antimony atoms are further linked by hydroxy bridges to give Sb2O2 rings and a quadridentate oxalate is coordinated between the two remaining antimony atoms of the ring; the counter ions are two cis-dioxalatodiphenylantimony anions.

  用草酸银处理二苯基溴化锑 (Ph2SbBrO)2 会产生一种新型离子产物，其中含有平面十二元环状锑-氧双阳离子，其中两对相邻的锑原子通过羟基桥进一步连接，形成 Sb2O2 环并且四齿草酸盐配位在环的剩余两个锑原子之间；抗衡离子是两个顺式二草酸二苯基锑阴离子。
• Reduction of antimony(V) by dithiophosphinates and the crystal structure of dimeric diphenylantimony(III) dimethyldithiophosphinate
  作者：Martin N. Gibbons、D. Bryan Sowerby、Christian Silvestru、Ionel Haiduc

  DOI：10.1016/0277-5387(96)00162-3

  日期：1996.9

  diorganodithiophosphinates and diphenylantimony(V) bromide oxide (SbPh2OBr)2, led to antimony reduction while dithiophosphinate oxidation followed a complex path varying in detail with the nature of the organic groups on dithiophosphinate. Antimony(III) dithiophosphinates, SbPh2(S2PR2) where R  Me, Et and Ph, have been isolated and characterised and an X-ray structure determination for the methyl derivative

  三种二有机二硫代次膦酸酯与二苯基溴化锑（V）氧化物（SbPh 2 OBr）2之间的反应导致锑的还原，而二硫代次膦酸酯的氧化遵循一条复杂的路径，该路径随二硫代次膦酸酯上有机基团的性质而变化。二硫代亚膦酸锑（III）SbPh 2（S 2 PR 2）（其中RMe，Et和Ph已被分离并表征），X射线结构测定的甲基衍生物显示出处于固态的弱缔合二聚体，介于（SbPh 2 S 2 PPh 2）2和[Sb（4-MeC 6 H 4）2 S 2 PEt] 2。
• Diphenylantimony(V) oxide halides and thiocyanate; the crystal structures of dimeric diphenylantimony(V) bromide oxide and tetrameric diphenylantimony(V) oxide fluoride and thiocyanate
  作者：I. Gary Southerington、Glynis E. Forster、Michael J. Begley、D. Bryan Sowerby

  DOI：10.1039/dt9950001995

  日期：——

  Dimers containing a four-membered Sb2O2 ring with antimony atoms in distorted trigonal-bipyramidal co-ordination were obtained when either diphenylantimony(III) chloride or bromide, was oxidised with tert-butyl hydroperoxide; the crystal structure of [SbPh(2)O(Br)](2) has been determined. Related reactions with the corresponding fluoride and thiocyanate gave products with the same stoichiometry but X-ray crystallography showed these are centrosymmetric tetramers, X(2)Ph(2)SbO(Ph(2)SbO(2)SbPh(2))OSbPh(2)X(2), which also contain a central four-membered ring. A possible mechanism for formation of these. tetramers is presented. Oxidation of phenylantimony dichloride and dibromide on the other hand gave only rearrangement and decomposition products.