decanedithioate de methyle | 100555-86-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代羰基化合物
• 英文名称: decanedithioate de methyle
• 英文别名: Methyl decanedithioate
• CAS: 100555-86-0
• 化学式: C₁₁H₂₂S₂
• 分子量: 218.428
• InChiKey: IOHDTZUEKVHMDW-UHFFFAOYSA-N

物化性质

• 沸点：
  296.2±9.0 °C(Predicted)
• 密度：
  0.953±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  57.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  decanedithioate de methyle 生成 (Z)-1-methylthio-1-sulfinyldecane
  参考文献：
  名称：

  METZNER, PATRICK;PHAM, THI NHAM, J. CHEM. SOC. CHEM. COMMUN.,(1988) N 5, 390-391

  摘要：

  DOI：
• 作为产物：
  描述：

  正癸酸 、 2,4-二(甲硫基)-1,3,2,4-二噻二磷杂丁环-2,4-二硫 以 氯苯 为溶剂， 以61%的产率得到decanedithioate de methyle
  参考文献：
  名称：

  Davy, Hubert; Metzner, Patrick, Journal of Chemical Research, Miniprint, 1985, # 8, p. 2701 - 2712

  摘要：

  DOI：

文献信息

• New Methods and Reagents in Organic Synthesis. 59. Lithium Trimethylsilydiazomethane: A New Synthon for the Preparation of 5-Substituted 1,2,3-Thiadiazoles
  作者：Toyohiko Aoyama、Yuji Iwamoto、Takayuki Shioiri

  DOI：10.3987/r-1986-03-0589

  日期：——
• Mono S-trimethylsilyl ketene dithioacetals as versatile tools for the synthesis of α-hydrazinodithioesters. A novel access to endothiopeptides.
  作者：Pierre Beslin、Philippe Marion

  DOI：10.1016/s0040-4039(00)91580-6

  日期：1992.2

  Mono-S-trimethylsilylketene dithioacetals have been prepared from dithioesters by the action of trimethylsilyl iodide formed in situ. They were reacted easily with dialkylazodicarboxylates to give good yields of alpha-hydrazinodithioesters. The latter were transformed into thioamides or endothiodipeptides by aminolysis either with an amine or an amino acid.
• Highly Chemoselective Oxidation of Dithioester Enethiolates to Sulfenates:  Application to the Synthesis of Ketene Dithioacetal <i>S</i>-Oxides
  作者：Franck Sandrinelli、Gaëlle Fontaine、Stéphane Perrio、Pierre Beslin

  DOI：10.1021/jo0492362

  日期：2004.10.1

  Enethiolates derived from dithioesters were efficiently converted into the corresponding vinyl sulfenates by oxidation with a unique N-sulfonyloxaziridine la derived from pinacolone. Subsequent alkylation with alkyl halides led to ketene dithioacetal S-oxides in good to excellent yields.
• Synthesis, characterization and blood cell labelling evaluation of new 99mTc nitrido radiopharmaceuticals with thioamide [R1C(=S)NHR2] derivatives
  作者：F. Mévellec、F. Demaimay、A. Roucoux、A. Moisan、N. Noiret、H. Patin

  DOI：10.1002/(sici)1099-1344(1998090)41:9<863::aid-jlcr134>3.0.co;2-h

  日期：1998.9

  The synthesis of a series of new Tc-99m-thioamide complexes with the [Tc=N](2+) nitrido core, in which the thioamide ligand substituents were varied to include different lengths of aliphatic alkyl chains or a phenyl group is reported TLC analysis shows that the complexes are neutral and lipophilic compounds. The Tc-99m complexes have a low blood cell labelling efficiency in whole blood compared to the reference complex of dithiocarbamate (TcN)-Tc-99m(Et(EtO)NCS2)(2).
• DAVY, H.;METZNER, P., J. CHEM. RES. SYNOP., 1985, N 8, 272
  作者：DAVY, H.、METZNER, P.

  DOI：——

  日期：——