Z-5-acetoxy-5-dodecene | 74879-47-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Z-5-acetoxy-5-dodecene
• 英文别名: [(Z)-dodec-5-en-5-yl] acetate
• CAS: 74879-47-3
• 化学式: C₁₄H₂₆O₂
• 分子量: 226.359
• InChiKey: UDZYXGFNBBSBNL-OWBHPGMISA-N

物化性质

• 沸点：
  289.9±9.0 °C(Predicted)
• 密度：
  0.882±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.59
• 重原子数：
  16.0
• 可旋转键数：
  9.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  三己基硼烷 、 1-己炔 、 lead(IV) acetate 以35%的产率得到
  参考文献：
  名称：

  MASUDA Y.; HOSHI M.; ARASE A., CHEM. LETT., 1980, NO. 4, 413-416

  摘要：

  DOI：

文献信息

• REACTION OF TRIALKYLBORANE WITH 1-ALKYNE AND LEAD(IV) ACETATE. A NEW REGIOSPECIFIC AND STEREOSPECIFIC ONE-POT SYNTHESIS OF ENOL ACETATES
  作者：Yuzuru Masuda、Masayuki Hoshi、Akira Arase

  DOI：10.1246/cl.1980.413

  日期：1980.4.5

  In the reaction of trialkylborane with 1-alkyne and lead(IV) acetate in hexane, one of the alkyl groups of trialkylborane migrated to the terminal carbon atom of the triple bond, giving regiospecifically an internal enol acetate and an internal alkyne as the main reaction products. The former compound had (Z)-configuration.

  在三烷基硼烷与 1-炔烃和乙酸铅（IV）在己烷中的反应中，三烷基硼烷的一个烷基迁移到三键的末端碳原子，区域特异性地得到内部烯醇乙酸酯和内部炔作为主要反应产品。前一种化合物具有(Z)-构型。
• WATER DISPERSION TYPE SUSTAINED RELEASE PREPARATION FOR RELEASING VOLATILE ACTIVE SUBSTANCE
  申请人：NISSIN CHEMICAL INDUSTRY CO., LTD.

  公开号：US20130230482A1

  公开（公告）日：2013-09-05

  There is provided a water dispersion for a sustained release preparation, the dispersion having viscosity at 25° C. of not more than 100 mPa·s and including polymer particles which are obtained by polymerizing ethylenically unsaturated group-containing monomers (A); at least one kind of a hydrophilic substance (B) in an amount of more than 0% by weight but not more than 20% by weight relative to a total amount of the ethylenically unsaturated group-containing monomers (A), being selected from a group consisting of a surfactant, a plasticizer and a moisturizer; polyvinyl alcohol (C) in an amount of more than 0% by weight but not more than 30% by weight relative to a total amount of the ethylenically unsaturated group-containing monomers (A), having a degree of saponification of more than 82 mol %; and water.

  提供一种水分散体，用于持续释放制剂，该分散体在25℃下的粘度不超过100mPa·s，包括通过聚合含有乙烯基不饱和基团的单体（A）而获得的聚合物颗粒；至少一种亲水性物质（B），相对于含有乙烯基不饱和基团的单体（A）的总量，重量百分比大于0％但不超过20％，所选自表面活性剂、增塑剂和保湿剂的组；聚乙烯醇（C），相对于含有乙烯基不饱和基团的单体（A）的总量，重量百分比大于0％但不超过30％，其皂化度大于82摩尔％；以及水。
• Sustained release dispenser comprising two or more sex pheromone substances and a pest control method
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP1459626A1

  公开（公告）日：2004-09-22

  Provided are a sustained release dispenser which can control the release of sex pheromone simultaneously toward two or more species of insect pests and can also release the sex pheromone in response to the generation period of insect pest and the pest control method toward two or more insect pests. Provided specifically is a sex pheromone sustained release dispenser comprising two or more sex pheromone substances, each substance being aliphatic derivative having 10 to 20 carbons, and first and second chambers wherein some or all of the sex pheromone substance having a smallest carbon number excluding a carbon number in a functional group is contained in a first polymer chamber and the remainder is contained in a second polymer chamber. Provided also is a pest control method for using the sex pheromone sustained release dispenser.

  本发明提供了一种性信息素持续释放分配器，该分配器可控制同时向两种或两种以上害虫释放性信息素，还可根据害虫的生成期释放性信息素，以及针对两种或两种以上害虫的害虫控制方法。特别提供了一种性信息素持续释放分配器，包括两种或两种以上的性信息素物质，每种物质都是具有 10 至 20 个碳原子的脂肪族衍生物，以及第一和第二室，其中具有最小碳原子数（不包括官能团中的碳原子数）的性信息素物质的一部分或全部包含在第一聚合物室中，其余部分包含在第二聚合物室中。还提供了一种使用性信息素持续释放分配器的害虫控制方法。
• US8834910B2
  申请人：——

  公开号：US8834910B2

  公开（公告）日：2014-09-16