[Mn(2-ethoxy-6-((2-hydroxyethylimino)methyl)phenol(-1H))(2-ethoxy-6-((2-hydroxyethylimino)methyl)phenol(-2H))(azido)]n*nCH3OH | 1408282-23-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Mn(2-ethoxy-6-((2-hydroxyethylimino)methyl)phenol(-1H))(2-ethoxy-6-((2-hydroxyethylimino)methyl)phenol(-2H))(azido)]n*nCH3OH
• CAS: 1408282-23-4
• 化学式: CH₄O*C₁₁H₁₃NO₃*C₁₁H₁₄NO₃*Mn*N₃
• 分子量: 544.466
• InChiKey: MJYOMZJVJUPWHO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.98
• 重原子数：
  36.0
• 可旋转键数：
  10.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  211.52
• 氢给体数：
  2.0
• 氢受体数：
  9.0

反应信息

• 作为产物：
  描述：

  甲醇 、 manganese(II) chloride tetrahydrate 、 2-ethoxy-6-[(2-hydroxyethylimino)methyl]phenol 、 sodium azide 反应 0.5h， 以68%的产率得到[Mn(2-ethoxy-6-((2-hydroxyethylimino)methyl)phenol(-1H))(2-ethoxy-6-((2-hydroxyethylimino)methyl)phenol(-2H))(azido)]n*nCH3OH
  参考文献：
  名称：

  Synthesis and Crystal Structure of A Novel Polymeric Manganese(IV) Complex Derived From the Schiff Base 2-Ethoxy-6-[(2-hydroxyethylimino)methyl]phenol

  摘要：

  A novel polymeric manganese(IV) complex, [Mn(L)(HL)(N3)] n center dot nCH3OH, has been synthesized from the Schiff base 2-ethoxy-6-[(2-hydroxyethylimino)methyl]phenol (H2L) with manganese chloride and sodium azide in methanol. The complex was characterized by elemental analysis, IR spectrum, and single-crystal X-ray diffraction. The Mn atom in the complex is coordinated by two phenolic oxygen, two imino nitrogen, and one hydroxyl oxygen atoms from two Schiff base ligands, and by one azido N atom, giving an octahedral coordination.

  DOI：

  10.1080/15533174.2012.684228