tris(trimethyl-l5-phosphaneyl)copper(IV) bromide | 148920-46-1

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: tris(trimethyl-l5-phosphaneyl)copper(IV) bromide
• CAS: 148920-46-1
• 化学式: C₉H₂₇BrCuP₃
• 分子量: 371.685
• InChiKey: DPWQIWIDAQBGEJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.92
• 重原子数：
  14.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  铜 、 三甲基膦 在 o-NH₂C₆H₄Br or o-CH₃OC₆H₄Br or p-CH₃OC₆H₄Br 作用下， 以 四氢呋喃 为溶剂， 以65%的产率得到tris(trimethyl-l5-phosphaneyl)copper(IV) bromide
  参考文献：
  名称：

  Reactivity of copper metal vapours with substituted bromobenzenes. Formation and molecular structure of Cu(PMe3)3Br

  摘要：

  Substituted bromobenzenes YArBr (Y=o-NH2, o-OMe or p-OMe) have been allowed to react with copper vapours at -108-degrees-C in THF solutions with a rotary metal atom apparatus. Addition of PMe3 or t-BuNC at different temperatures to these solutions led to the isolation of Cu(PMe3)3Br (1) and (t-BuNC)4CuBr (2), respectively. The crystal structure of 1 has been determined by X-ray diffraction. Crystals of 1 belong to the cubic space group Pa3BAR with Z=8, a=15.7451 angstrom, D(c)=1.26 g cm-3, R=0.0395. Analyses of the THF solutions showed the presence of reduction and coupling products of the aromatic substrates together with a coupling product arising from the bromoarenes and THF. These results suggest that the reactions between haloarenes and copper vapours proceed through dehalogenation of the haloarenes with formation of copper bromide and of aryl radicals which are responsible for the observed organic products.

  DOI：

  10.1016/s0020-1693(00)91455-5