Yb(tris(trimethylsilylamide)(benzophenone)) | 141216-50-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Yb(tris(trimethylsilylamide)(benzophenone))
• CAS: 141216-50-4
• 化学式: C₃₁H₆₄N₃OSi₆Yb
• 分子量: 836.422
• InChiKey: UCADNACOVVHZQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二苯甲酮 、 tris(bis(trimethylsilyl)amido)ytterbium(III) 以 甲苯 、 正戊烷 为溶剂， 生成 Yb(tris(trimethylsilylamide)(benzophenone))
  参考文献：
  名称：

  Benzophenone complexes of the lanthanides: Synthesis of [Ln{N(SiMe3)2}3(Ph2CO)] (L = La, Eu, Tb, Yb or Y) and X-ray crystal structure of the terbium complex

  摘要：

  The four coordinate complexes [LnL3(Ph2CO)] [Ln = La, Eu, Tb, Yb or Y; L = N(SiMe3)2] have been prepared by reaction of [LnL3] with one equivalent of Ph2 CO. The crystal and molecular structure of [TbL3(Ph2CO)] have been determined by X-ray diffraction [monoclinic P2(1)/n; a = 11.738(4), b = 31.425(4), c = 12.729(2) angstrom; beta = 110.16(3)-degrees; Z = 4; R = 0.0437 for 5276 unique reflections]. The complex has a distorted tetrahedral arrangement of ligand atoms around terbium, and Ph2CO is coordinated through oxygen. Spectroscopic (H-1 NMR, C-13 NMR, IR and UV-vis) and analytical data are consistent with this structure for Ln = La, Eu, Yb or Y. Variable temperature H-1 NMR studies of [EuL3(Ph2CO)] show that rotation about the Eu-N bonds is frozen out at 203 K, but there is still rapid rotation about the Eu-O bond at 180 K.

  DOI：

  10.1016/s0277-5387(00)83194-0