1-(2-fluorobenzyl)-3,3-dimethylspiro[indoline-2,3'-[3H]-naphtho[2,1-b](1,4)-oxazine] | 104088-76-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 1-(2-fluorobenzyl)-3,3-dimethylspiro[indoline-2,3'-[3H]-naphtho[2,1-b](1,4)-oxazine]
• 英文别名: 1'-[(2-Fluorophenyl)methyl]-3',3'-dimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]
• CAS: 104088-76-8
• 化学式: C₂₈H₂₃FN₂O
• 分子量: 422.502
• InChiKey: VATZCMYLMWNNEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  24.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-[(2-fluorophenyl)methyl]-3,3-dimethyl-2-methylideneindole 、 1-亚硝基-2-萘酚 生成 1-(2-fluorobenzyl)-3,3-dimethylspiro[indoline-2,3'-[3H]-naphtho[2,1-b](1,4)-oxazine]
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Spiro-oxazine compounds and preparation thereof and photochromic shaped article
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0171909A1

  公开（公告）日：1986-02-19

  A spiro-oxazine compound of the formula (A): wherein R1, R2, R3, R4, R5, R6 and R7 independently represent hydrogen, (C1 or 2) alkyl, halogenated C1-2 alkyl, C1-2 alkoxy, halogen or nitro, R is unsubstituted or substituted phenyl or naphthyl, and n is 1 to 5, is valuable as a photochromic material and exhibits enhanced fatigue resistance in photocolorability. The spiro-oxazine compound is prepared by reacting a precursor of the spiro-oxazine compound of the formula (A), which has a substituent of the formula: -(CH2)n- R in the nitrogen atom of the indoline nucleus, with an α-nitroso-β-naphthol.

  一种式（A）的螺嗪化合物： 其中 R1、R2、R3、R4、R5、R6 和 R7 独立地代表氢、（C1 或 2）烷基、卤代 C1-2 烷基、C1-2 烷氧基、卤素或硝基，R 是未取代或取代的苯基或萘基，n 是 1 至 5，该化合物作为光致变色材料非常有价值，在光致变色性方面具有更强的抗疲劳性。 螺噁嗪化合物的制备方法是将具有以下取代基的式（A）螺噁嗪化合物前体进行反应： -(CH2)n- R 的前体与 α-亚硝基-β-萘酚反应。
• A non-glaring laminated body, a coated non-glaring laminated body, a non-glaring material, and a method for producing the non-glaring material
  申请人：MGC Filsheet Co., Ltd.

  公开号：EP1916097A2

  公开（公告）日：2008-04-30

  [Problem to be solved] The present invention provides a non-glaring material having an excellent property to cut ultraviolet rays, and having an excellent appearance and optical property as well as easy producibility and processibility, and a method for producing the non-glaring material. [Means to solve the problem] A non-glaring laminated body consisting of two transparent plastic material layers, a polarizing film layer which is held between the two transparent plastic material layers, and a synthetic adhesive layer which adheres the plastic material layer to the polarizing film layer, wherein at least one of the adhesive layers includes a fluorescent whitening agent and an ultraviolet ray absorber.

  [有待解决的问题］ 本发明提供了一种具有优异的紫外线切割性能、优异的外观和光学性能以及易于生产和加工的不刺眼材料，以及生产这种不刺眼材料的方法。 [解决问题的方法］ 一种不刺眼层压体，由两层透明塑料材料层、夹在两层透明塑料材料层之间的偏光膜层和将塑料材料层粘在偏光膜层上的合成粘合剂层组成，其中至少一层粘合剂层包括荧光增白剂和紫外线吸收剂。
• Organic light-emitting display apparatus
  申请人：Samsung Display Co., Ltd.

  公开号：US10249693B2

  公开（公告）日：2019-04-02

  An organic light-emitting display apparatus for selectively realizing circular polarization according to external light conditions, including a substrate; an organic light-emitting device on the substrate; a sealing member on the organic light-emitting device; a phase retardation layer on a surface of the substrate, the organic light-emitting device, or the sealing member; and a linear polarization layer on another surface of the substrate, the organic light-emitting device, or the sealing member, wherein the linear polarization layer is located to be closer to a source of external light than the phase retardation layer, and wherein the linear polarization layer comprises a photochromic material.

  一种根据外部光照条件选择性实现圆偏振的有机发光显示装置，包括基板；基板上的有机发光器件；有机发光器件上的密封部件；基板、有机发光器件或密封部件的一个表面上的相位延迟层，以及基板、有机发光器件或密封部件的另一个表面上的线性偏振层；以及位于基板、有机发光器件或密封部件的另一表面上的线性偏振层，其中线性偏振层的位置比相位延迟层更靠近外部光源，并且线性偏振层包括光致变色材料。
• Polyurethane based inks for writing instruments
  申请人：BIC Corporation

  公开号：US20030055127A1

  公开（公告）日：2003-03-20

  A non-erasable ink composition suitable for use in writing instruments is described comprising an isocyanate free thermoplastic polyurethane resin, a colorant and an organic solvent. The ink composition may also include a second resin, plasticizers, antioxidants, corrosion inhibitors, lubricants, chemical dispersants, and surfactants. The inks of the present invention exhibit a smooth writing performance and non-seepage.

  描述了一种适用于书写工具的不可擦除油墨组合物，它由不含异氰酸酯的热塑性聚氨酯树脂、着色剂和有机溶剂组成。油墨组合物还可包括第二种树脂、增塑剂、抗氧化剂、腐蚀抑制剂、润滑剂、化学分散剂和表面活性剂。本发明的油墨具有平滑的书写性能和不渗水的特点。
• ——
  作者：YAMAMOTO SINITI、 TANIGUTI TAKASI

  DOI：——

  日期：——