Phenoxymethyl-benzyl-aether | 92495-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Phenoxymethyl-benzyl-aether
• 英文别名: formaldehyde-(benzyl-phenyl-acetal)；Phenylbenzylformal；Phenoxymethoxymethylbenzene
• CAS: 92495-85-7
• 化学式: C₁₄H₁₄O₂
• 分子量: 214.264
• InChiKey: CIARPZWCAXEHQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯甲醇 在 盐酸 、 乙醇 作用下， 生成 Phenoxymethyl-benzyl-aether
  参考文献：
  名称：

  Sabetay; Schving, Bulletin de la Societe Chimique de France, 1928, vol. <4> 43, p. 1344

  摘要：

  DOI：

文献信息

• High-Throughput Screening Protocol for the Coupling Reactions of Aryl Halides Using a Colorimetric Chemosensor for Halide Ions
  作者：Min Sik Eom、Jieun Noh、Han-Sung Kim、Soyeon Yoo、Min Su Han、Sunwoo Lee

  DOI：10.1021/acs.orglett.6b00300

  日期：2016.4.15

  efficiency as a tool for high-throughput screening (HTS) of transition-metal-catalyzed coupling reactions was investigated. It showed a high selectivity for halide ions. When the PAR–2Hg2+ complex was used in the Suzuki coupling reaction and C–H activated coupling reaction with aryl bromides, the quantitative and qualitative conversions of aryl halides were obtained from the reaction mixture color change

  制备了4-（2-吡啶基偶氮）间苯二酚（PAR-2Hg 2+）的汞络合物，卤离子化学传感器，其作为过渡金属催化的偶联反应高通量筛选（HTS）的工具的效率为调查。它显示出对卤离子的高选择性。当将PAR-2Hg 2+络合物用于Suzuki偶联反应和CH-H与芳基溴的活化偶联反应时，从反应混合物的颜色变化获得了芳基卤化物的定量和定性转化。
• Novel compounds and their use
  申请人：——

  公开号：US20020147200A1

  公开（公告）日：2002-10-10

  A compound of the general formula (I): 1 wherein R 1 , R 2 , X, Y and Z are as described in the specification.

  通式（I）的化合物：其中R1、R2、X、Y和Z如规范中所述。
• METHOD FOR PRODUCING SILICON COMPOUND
  申请人：Nakagawa Hisashi

  公开号：US20100261925A1

  公开（公告）日：2010-10-14

  A method of producing a silicon compound shown by the following general formula (7) includes reacting an organomagnesium compound shown by the following general formula (1) with an organosilane compound shown by the following general formula (2) in a solvent that contains at least one compound selected from a compound shown by the following general formula (3), a compound shown by the following general formula (4), a compound shown by the following general formula (5), and a compound shown by the following general formula (6).

  生产以下通式（7）所示的硅化合物的方法包括在至少含有以下通式（3）所示的化合物、以下通式（4）所示的化合物、以下通式（5）所示的化合物和以下通式（6）所示的化合物中的溶剂中，将以下通式（1）所示的有机镁化合物与以下通式（2）所示的有机硅化合物反应。
• Mamedov,S. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3567 - 3571
  作者：Mamedov,S. et al.

  DOI：——

  日期：——
• Ink Jet Recording Ink Set and Ink Jet Image Recording Method
  申请人：Makuta Toshiyuki

  公开号：US20090073246A1

  公开（公告）日：2009-03-19

  Disclosed are an ink jet recording ink set which is suppressed in bleeding and shot droplet interference and can form a high quality image and an ink jet image recording method. The ink jet recording ink set has plural liquids including at least a first liquid and a second liquid. The second liquid contains a polymerizable compound and the first liquid contains a high-boiling point organic solvent and the high-boiling organic solvent meets any one of the following requirements (A) to (C) and an ink jet image recording method includes supplying a first and a second liquid simultaneously or sequentially to a recording medium such that both liquids are in contact with each other, to form an image: (A) it has a viscosity of 100 mPa·s or less at 25° C. and a viscosity of 30 mPa·s or less at 60° C. and has a boiling point of 100° C. or higher, (B) it is represented by the following formula (I), and (C) it is represented by the following formula (II):