[[bis((diphenylphosphinoethyl)phenylphosphino)methane-PPP]PtMe]Cl | 683810-61-9

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: [[bis((diphenylphosphinoethyl)phenylphosphino)methane-PPP]PtMe]Cl
• CAS: 683810-61-9
• 化学式: C₄₂H₄₃OP₄Pt*Cl
• 分子量: 918.231
• InChiKey: MQFYCSFCSTVPAY-VJRTURPNSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)platinum(II) 、 ((R)-(2-(2-二苯基磷酰)乙基)(苯基)磷酰)((S)-(2-二苯基磷酰)乙基)(苯基)磷酰)甲烷 以 丙酮 为溶剂， 生成 [[bis((diphenylphosphinoethyl)phenylphosphino)methane-PPP]PtMe]Cl
  参考文献：
  名称：

  Approaches to bi- and trimetallic platinum and palladium complexes using the DPPEPM ligand

  摘要：

  Bis {(diphenylphosphinoethyl)phenylphosphino}methane (DPPEPM) reacts with [PtR2(cod)] in 1:1 ratio to give [PtR2? (DPPEPM-PP)] (2a, R = Me; 2b, R = Ph), whereas with [PtCl2(cod)] or [PdCl2(cod)] it yields the ionic species [M(DPPEPM-PP)(2)](2+) (3 and 4). With [MClMe(cod)], the product is [MMe(DPPEPM-PPP)](+) (5, M Pt; 6, M = Pd), in which one of the internal P atoms of the ligand is uncoordinated. These complexes undergo oxidation of the free P atom to give 7 and 8 on standing in solution. Complexes 2-4 may be used to construct bimetallic and trimetallic mixed metal complexes. The molecular structures of 7 and [PtMe2(mu-DPPEPM)PdCl2] (11) are reported. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.08.004