sodium N,N-dimethoxyphosphorylbenzamide | 85014-38-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium N,N-dimethoxyphosphorylbenzamide
• 英文别名: sodium salt of benzoic-dimethyl-phosphoric imide；sodium salt of N-(O,O-dimethylphosphoryl)benzamide；dimethylbenzoylamidophosphate sodium salt；dimethylbenzoylamidophosphate sodium；sodium;N-dimethoxyphosphorylbenzenecarboximidate
• CAS: 85014-38-6
• 化学式: C₉H₁₁NO₄P*Na
• 分子量: 251.154
• InChiKey: LDFKRRWMNLXEFF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.39
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  53.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  sodium N,N-dimethoxyphosphorylbenzamide 、 三乙基氧翁四氟硼酸 生成 N-benzoyl-O,O-dimethyl-O-ethylphosphorimidate
  参考文献：
  名称：

  MIZRAHI, V.;HENDRICKSE, T.;MODRO, T. A., CAN. J. CHEM., 1983, 61, N 1, 118-123

  摘要：

  DOI：
• 作为产物：
  描述：

  Phosphorsaeure-dimethylester-benzamid 以 甲醇 为溶剂， 反应 2.0h， 以59.5%的产率得到sodium N,N-dimethoxyphosphorylbenzamide
  参考文献：
  名称：

  Zabirov, N. G.; Shamsevaleev, F. M.; Shcherbakova, V. A., Journal of general chemistry of the USSR, 1990, vol. 60, # 9.1., p. 1783 - 1789

  摘要：

  DOI：

文献信息

• First examples of carbacylamidophosphate pentanuclear hydroxo-complexes: Synthesis, structure, luminescence and magnetic properties
  作者：Nataliia S. Kariaka、Julia A. Rusanova、Sergii S. Smola、Sergey V. Kolotilov、Kateryna O. Znovjyak、Marek Weselski、Tatiana Yu Sliva、Vladimir M. Amirkhanov

  DOI：10.1016/j.poly.2015.12.052

  日期：2016.2

  single-molecule magnet behavior for 3 were found at 2 K. Phosphorescence, emission and excitation spectra at 298 K and 77 K for the complexes were measured, as well as luminescence decay times were determined. The compounds 1 and 3 showed intense luminescence with decay time at 298 K equal to 0.66 and 1.44 ms respectively. Intrinsic quantum yield for 1 determined from its emission spectrum was found to be 25%.

  的组合物LN pentanuclear carbacylamidophosphate复合物的第一代表5大号6（μ-L）4（μ 3 -OH）4（μ 4 -OH）（LN III  =铕（1），钆（2），TB（3） ，L -  [C = dimethylbenzoylamidophosphate离子6 ħ 5（O）（OCH C（O）-N-P 3）2 ] - ）获得。单晶X-射线分析揭示的该多核芯1包含五个铕离子，由μ连接3 -和μ 4个-hydroxo组和carbacylamidophosphate配体。化合物1 - 3被认为是同构。磁化率的温度依赖性（χ中号化合物）1和2可以通过铕自旋轨道耦合来解释III离子或四个的Gd反铁磁交换相互作用III位于Gd组成的碱离子5金字塔，分别。在3的情况下，的值χ中号随温度下降从300K到50 K，并且然后增大降温过程中降低下来，直到2 K.这样的行为可以通
• New Luminescent Lanthanide Tetrakis‐Complexes NEt ₄ [LnL ₄ ] Based on Dimethyl‐N‐Benzoylamidophosphate
  作者：Nataliia S. Kariaka、Victor A. Trush、Viktoriya V. Dyakonenko、Svitlana V. Shishkina、Sergii S. Smola、Nataliia V. Rusakova、Tetiana Y. Sliva、Paula Gawryszewska、Albano N. Carneiro Neto、Oscar L. Malta、Vladimir M. Amirkhanov

  DOI：10.1002/cphc.202200129

  日期：2022.7.19

  counter ion NEt4+ to the [LnL4]− complexes instead of Cs+ significantly influences the complexes’ physical properties. The complexes form at least two types of crystals. Europium and terbium compounds demonstrate luminescence with decay time 2.2 and 2.3 ms, respectively. Unusually high band intensity of 5D0→7F4 transition is observed in the luminescence spectrum of NEt4[EuL4] and discussed based on theoretical

  报道了一系列明亮发光的镧系元素四络合物NEt 4 [LnL 4 ] 与二甲基-N-苯甲酰氨基磷酸酯。将抗衡离子NEt 4 +引入[LnL 4 ] -配合物而不是Cs +显着影响配合物的物理性质。配合物形成至少两种类型的晶体。铕和铽化合物分别以 2.2 和 2.3 毫秒的衰减时间显示发光。在NEt 4 [ EuL 4 _ _ _ _ _ _] 并根据理论计算进行讨论。
• Coordination compounds based on CAPh type ligand: synthesis, structural characteristics and luminescence properties of tetrakis-complexes CsLnL₄ with dimethylbenzoylamidophosphate
  作者：Nataliia S. Kariaka、Victor A. Trush、Volodymyr V. Medviediev、Viktoriya V. Dyakonenko、Oleg V. Shishkin、Sergii S. Smola、Evgen M. Fadeyev、Nataliia V. Rusakova、Vladimir M. Amirkhanov

  DOI：10.1080/00958972.2015.1115024

  日期：2016.1.2

  Searching for prospective luminescent materials, the series of new lanthanide coordination compounds CsLnL(4) (Ln=La, Pr, Nd, Sm - Er, and Yb; L-=C6H5CONPO(OCH3)(2)}(-)) was synthesized. X-ray diffraction studies of CsNdL4 and CsYbL4 have been performed establishing polymeric structures of the tetrakis-complexes built from [LnL(4)](-) anions and cesium cations functioning as linkers. The IR, absorption, emission, excitation spectra, and decay time measurements at 298 and 77K, as well as thermal gravimetric analyses, were used to characterize the complexes.[GRAPHICS].
• ZABIROV, N. G.;POZDEEV, O. K.;SHAMSEVALEEV, F. M.;CHERKASOV, R. A.;GILMAN+, XIM.-FARMATS. ZH., 23,(1989) N, S. 600-602
  作者：ZABIROV, N. G.、POZDEEV, O. K.、SHAMSEVALEEV, F. M.、CHERKASOV, R. A.、GILMAN+

  DOI：——

  日期：——
• Mizrahi, Valerie; Modro, Tomasz A., Phosphorus and Sulfur and the Related Elements, 1983, vol. 18, p. 141 - 144
  作者：Mizrahi, Valerie、Modro, Tomasz A.

  DOI：——

  日期：——