[4-chloro-2-[2-(dimethylamino)ethyliminomethyl]phenolato]thiocyanatonickel(II) | 912552-45-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [4-chloro-2-[2-(dimethylamino)ethyliminomethyl]phenolato]thiocyanatonickel(II)
• CAS: 912552-45-5
• 化学式: C₁₂H₁₄ClN₃NiOS
• 分子量: 342.472
• InChiKey: QTDDHWTXPRJCOU-LIYVDSPJSA-M

反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 nickel(II) acetate tetrahydrate 、 N,N-二甲基乙二胺 、 5-氯代水杨醛 以 甲醇 、 水 为溶剂， 生成 [4-chloro-2-[2-(dimethylamino)ethyliminomethyl]phenolato]thiocyanatonickel(II)
  参考文献：
  名称：

  Two different structures controlled by small secondary ligands: {4-chloro-2-[2-(dimethylamino)ethyliminomethyl]phenolato}thiocyanatonickel(II) andcatena-poly[[{4-chloro-2-[2-(dimethylamino)ethyliminomethyl]phenolato}nickel(II)]-μ-azido]

  摘要：

  The title complexes, [Ni(C11H14ClN2O)(NCS)], (I), and [Ni(C11H14ClN2O)(N-3)](n), (II), are two different structures constructed from the same Schiff base ligand, viz. 4-chloro-2[ 2-(dimethylamino) ethyliminomethyl] phenol, and different linear triatomic secondary ligands, viz. thiocyanate for ( I) and azide for ( II). In mononuclear ( I), the Ni-II atom is four-coordinated in a square-planar geometry by the N, N', O-donor set of the Schiff base and by the N atom of the terminal thiocyanate ligand, while in polynuclear ( II), the Ni-II atom is five-coordinated in a square-pyramidal geometry by the N, N', O-donor set of the Schiff base and by two N atoms from two bridging azide groups.

  DOI：

  10.1107/s0108270106003118