1,9-Diphenyl-nonan | 3976-48-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,9-Diphenyl-nonan
• 英文别名: 1,9-Diphenylnonane；9-phenylnonylbenzene
• CAS: 3976-48-5
• 化学式: C₂₁H₂₈
• 分子量: 280.453
• InChiKey: WXQQXUQJVUAIDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  21
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,9-Diphenyl-nonan 在 二硫化碳 、 二(alpha-氯乙基)醚 、 tin(ll) chloride 作用下， 生成 1,9-bis-(4-chloromethyl-phenyl)-nonane
  参考文献：
  名称：

  Jaunin; Baer, Helvetica Chimica Acta, 1958, vol. 41, p. 104,106

  摘要：

  DOI：
• 作为产物：
  描述：

  壬二酰氯 在 氢氧化钾 、 三氯化铝 、 肼 作用下， 以 乙二醇 为溶剂， 生成 1,9-Diphenyl-nonan
  参考文献：
  名称：

  Conformational study of the higher [n.n]paracylophanes: evaluation as potential hosts for molecular halogens and benzenes

  摘要：

  A fundamental study of the conformations of [7.7]-, [8.8]-, [9.9]-, [11.11]- and octamethyl[8.8]-paracyclophanes in the solid state shows that the [odd,odd] members of the series possess parallel, symmetrically disposed benzene rings. A new genre of inclusion phenomenon based on donor-halogen EDA interactions is also defined and the potential of cyclophanes to act as hosts both in this capacity and to benzenes is discussed.

  DOI：

  10.1039/p19960001141

文献信息

• Iridium-Catalyzed Reactions of ω-Arylalkanols to α,ω-Diarylalkanes
  作者：Yasushi Obora、Yuka Anno、Ryuhei Okamoto、Toyomi Matsu-ura、Yasutaka Ishii

  DOI：10.1002/anie.201104452

  日期：2011.9.5

  The long and the short of it: An atom‐economical route to α,ω‐diarylalkanes from ω‐arylalkanols was achieved by a direct one‐step method, or a sequential two‐step method depending on the alkyl chain length. The reaction proceeded through the formation of β‐methylhydroxy‐α,ω‐diarylalkanes by dehydrogenation/β‐alkylation, followed by dehydrogenation/decarbonylation.

  它的长短：通过直接一步法或取决于烷基链长的连续两步法，从ω-芳基链烷醇制得α，ω-二芳基烷烃的原子经济途径。该反应通过脱氢/β-烷基化，然后脱氢/脱羰基，形成β-甲基羟基-α，ω-二芳基烷烃来进行。
• Borsche; Wollemann, Chemische Berichte, 1912, vol. 45, p. 3717
  作者：Borsche、Wollemann

  DOI：——

  日期：——
• Kuck,D.; Gruetzmacher,H.-F., Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1979, vol. 34, p. 1750 - 1764
  作者：Kuck,D.、Gruetzmacher,H.-F.

  DOI：——

  日期：——
• Ogawa, Kogyo Kagaku zasshi / Journal of the Society of Chemical Industry, 1951, vol. 54, p. 117
  作者：Ogawa

  DOI：——

  日期：——
• Conformational study of the higher [n.n]paracylophanes: evaluation as potential hosts for molecular halogens and benzenes
  作者：Mark Mascal、Jean-Luc Kerdelhué、Andrei S. Batsanov、Michael J. Begley

  DOI：10.1039/p19960001141

  日期：——

  A fundamental study of the conformations of [7.7]-, [8.8]-, [9.9]-, [11.11]- and octamethyl[8.8]-paracyclophanes in the solid state shows that the [odd,odd] members of the series possess parallel, symmetrically disposed benzene rings. A new genre of inclusion phenomenon based on donor-halogen EDA interactions is also defined and the potential of cyclophanes to act as hosts both in this capacity and to benzenes is discussed.