(E)-1,2-dibutyldiazene 1,2-dioxide | 26049-02-5

• 分子结构分类: 有机化合物
• 英文名称: (E)-1,2-dibutyldiazene 1,2-dioxide
• 英文别名: Dimeres 1-Nitroso-butan；1-Nitroso-butan-Dimeres；trans-1-Azodioxy-butan；dibutyl-diazene dioxide；Dibutyl-diazen-dioxid；(E)-butyl-[butyl(oxido)azaniumylidene]-oxidoazanium
• CAS: 26049-02-5
• 化学式: C₈H₁₈N₂O₂
• 分子量: 174.243
• InChiKey: DWWSWWGVFPFHGF-MDZDMXLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  57.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  亚硝酸正戊酯 生成 (E)-1,2-dibutyldiazene 1,2-dioxide
  参考文献：
  名称：

  331.用亚硝酸烷基酯制备亚硝基链烷烃

  摘要：

  DOI：

  10.1039/jr9560001670

文献信息

• Action d'un tétrafluoroborate d'oxaziridinium sur les amines et les imines
  作者：Gilles Hanquet、Xavier Lusinchi

  DOI：10.1016/s0040-4020(01)89569-7

  日期：1994.1

  The Oxaziridinium salt 1 derived from dihydroisoquinolin is an oxygen transfer reagent to primary amines leading to nitrosoderivatives (if R= Alkyl) or nitro compounds (if R= Aryl), to tertiary amines leading to N-oxides, and to secondary amines and imines leading to the corresponding nitrone.

  衍生自二氢异喹啉的恶唑烷鎓盐1是向伯胺的氧转移试剂，伯胺可导致亚硝基衍生物（如果R =烷基）或硝基化合物（如果R =芳基），叔胺导致N-氧化物，仲胺和亚胺导致到相应的硝酮。
• On the Oxidation of Different Iminic Bonds by Excess of 3-Chloroperbenzoic Acid
  作者：Luigino Troisi、Marina Carrozzo、Cinzia Citti、Aurelia Falcicchio、Rosmara Mansueto、Francesca Rosato、Giuseppe Cannazza

  DOI：10.1055/s-0032-1317760

  日期：——

  In the present work the behavior of different substituted iminic bonds toward the oxidative action of 3-chloroperbenzoic acid is reported. The C=N bond was or was not oxidized to oxaziridines, amides, oximes, nitroso-, nitro-, and azodioxy compounds depending on the substituents at the iminic group and on the ­imine/MCPBA stoichiometric ratio.

  在目前的工作中，报告了不同取代亚胺键对 3-氯过苯甲酸氧化作用的行为。根据亚胺基上的取代基和亚胺/MCPBA 化学计量比，C=N 键是否被氧化为氧氮丙啶、酰胺、肟、亚硝基-、硝基-和偶氮二氧基化合物。
• Dimethyldioxirane oxidation of primary amines
  作者：Jack K. Crandall、Thierry Reix

  DOI：10.1021/jo00051a017

  日期：1992.12

  Several primary amines 2 have been oxidized with dimethyldioxirane (1) under a variety of conditions. Mixtures of dimeric nitrosoalkanes 4 and oximes 5 were typically obtained with solutions of the oxidant in excess. In several instances, nitrones 12 were found as byproducts in these reactions. In situ oxidations using oxone in buffered aqueous acetone solution also gave nitrosoalkanes 4 and oximes 3 as important products; in addition, oxaziridines 11 were obtained in significant amounts in biphasic procedures containing methylene chloride. The corresponding nitroalkanes 3 were not formed in major amounts in either oxidation procedure, unless large excesses of oxidant were used. These results are discussed in terms of the several competing processes which occur under the different reaction conditions.
• Collin,G. et al., Justus Liebigs Annalen der Chemie, 1967, vol. 702, p. 55 - 67
  作者：Collin,G. et al.

  DOI：——

  日期：——
• Mackor,A.; de Boer,T.J., Recueil des Travaux Chimiques des Pays-Bas, 1970, vol. 89, p. 151 - 158
  作者：Mackor,A.、de Boer,T.J.

  DOI：——

  日期：——