4-氰基苯甲脒盐酸盐 | 117837-77-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-氰基苯甲脒盐酸盐
• 英文名称: 4-cyanobenzamidine hydrochloride
• 英文别名: 4-cyanobenzenecarboximidamide;hydrochloride
• CAS: 117837-77-1
• 化学式: C₈H₇N₃*ClH
• 分子量: 181.625
• InChiKey: IKVRHGPKSBUMIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.26
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  73.7
• 氢给体数：
  3
• 氢受体数：
  2

安全信息

• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为反应物：
  描述：

  4-氰基苯甲脒盐酸盐 在 sodium hydroxide 、 sodium ethanolate 作用下， 以 乙醇 为溶剂， 反应 64.0h， 生成 4,6-dihydroxy-2-(p-cyanophenyl)-5-(p-butoxyphenylazo)pyrimidine
  参考文献：
  名称：

  Arylazopyrimidines as dichroic dyes for liquid crystals

  摘要：

  DOI：

  10.1007/bf00531662
• 作为产物：
  描述：

  对苯二腈 在 sodium methylate 、 氯化铵 作用下， 以 甲醇 为溶剂， 反应 110.0h， 生成 4-氰基苯甲脒盐酸盐
  参考文献：
  名称：

  Hammett研究芳基二氯甲基碳负离子反应。

  摘要：

  [反应：见正文]测量速率常数，测定氯离子捕获对位取代的苯基氯卡宾以形成芳基二氯甲基碳负离子，以及将这些碳负离子添加到丙烯腈中。Hammett分析得出前者反应的rho = +0.86，后者反应的rho = -2.65。

  DOI：

  10.1021/ol060188c

文献信息

• 신규 방향족 복소 고리 유도체, 유기 일렉트로 루미네선스 소자용 재료, 유기 일렉트로 루미네선스 소자용 재료 용액 및 유기 일렉트로 루미네선스 소자
  申请人：IDEMITSU KOSAN CO., LTD. 이데미쓰 고산 가부시키가이샤(519980963384)

  公开号：KR20150053913A

  公开（公告）日：2015-05-19

  정공 수송능과 전자 수송능을 분자 내에 겸비하는 특정한 구조를 갖는 신규 방향족 복소 고리 유도체, 그리고 상기 방향족 복소 고리 유도체를 사용한 유기 일렉트로 루미네선스 소자용 재료, 유기 일렉트로 루미네선스 소자용 재료 용액 및 유기 일렉트로 루미네선스 소자를 제공한다.

  具有同时具备金属导电性和电子传输性的特定结构的新型芳香族复杂环衍生物，以及用于有机电致发光器件的有机电致发光器件材料，有机电致发光器件材料溶液和有机电致发光器件。
• Base‐Mediated Decarboxylative [3+2] Annulation of Ethynyl Benzoxazinanones and Benzimidamides: Synthesis of Imidazole Derivatives
  作者：Lan Wang、Feng Jiang、Xing Gao、Wei Wang、Yongjun Wu、Hongchao Guo、Bing Zheng

  DOI：10.1002/adsc.202001550

  日期：2021.4.13

  A base‐mediated decarboxylative [3+2] annulation of trimethylsilylethynyl benzoxazinanones and benzimidamides hydrochloride was achieved under mild reaction conditions to give various imidazole derivatives in high yields. Notably, it demonstrated a new reaction mode of alkynyl benzoxazinanones.

  在温和的反应条件下，实现了碱介导的三甲基甲硅烷基乙炔基苯并恶嗪酮与盐酸苯并咪酰胺类化合物的[3 + 2]环化反应，以高收率得到了各种咪唑衍生物。值得注意的是，它展示了炔基苯并恶嗪酮的新反应模式。
• [EN] NEW TRIAZINE AS PHOTO INITIATORS AND THEIR PREPARATION<br/>[FR] NOUVEAUX PHOTO-INITIATEURS EN TRIAZINE ET LEUR PRÉPARATION
  申请人：COVESTRO DEUTSCHLAND AG

  公开号：WO2016207161A1

  公开（公告）日：2016-12-29

  The present invention relates to new triazine photoinitiators, a new process for their preparation, and a photopolymer composition comprising a photopolymerizable component and the new triazine photoinitiators. Further aspects of the present invention are a photopolymer comprising said photopolymer composition, a holographic medium which comprises such a photopolymer, a hologram comprising the holographic medium, and a device such a display, chip card, security document, bank note and / or holographic optical element comprising said hologram.

  本发明涉及新的三嗪光引发剂，其制备的新工艺，以及包括光聚合组分和新的三嗪光引发剂的光聚合物组合物。本发明的进一步方面包括包括所述光聚合物组合物的光聚合物，包括这样一种光聚合物的全息介质，包括全息介质的全息图，以及包括所述全息图的显示器、芯片卡、安全文件、纸币和/或全息光学元件的装置。
• N-(.alpha.-Aminoalkylidene)phosphor- and phosphonamidates, and method
  申请人：Velsicol Chemical Corporation

  公开号：US04046884A1

  公开（公告）日：1977-09-06

  This invention discloses chemical compounds of the formula ##STR1## wherein X.sup.1 and X.sup.2 are independently selected from the group consisting of oxygen and sulfur; m is the integer 0 or 1; R.sup.1 is selected from the group consisting of hydrogen and alkyl; R.sup.2 is alkyl; R.sup.3 and R.sup.4 are independently selected from the group consisting of hydrogen and alkyl; R.sup.5 is selected from the group consisting of hydrogen, alkyl, alkoxy, alkylthio, amino and ##STR2## WHEREIN Y is selected from the group consisting of alkyl, halogen, alkoxy, alkylthio, nitro and cyano; and n is an integer from 0 to 3; and R.sup.6 is selected from the group consisting of alkyl, alkenyl, alkoxyalkyl and ##STR3## WHEREIN Z is selected from the group consisting of alkyl, halogen, alkoxy, alkylthio, nitro and cyano; and p is an integer from 0 to 3.

  该发明揭示了化学化合物的结构式如下：其中X^1和X^2分别独立地选自氧和硫的组成群；m为整数0或1；R^1选自氢和烷基的组成群；R^2为烷基；R^3和R^4分别独立地选自氢和烷基的组成群；R^5选自氢、烷基、烷氧基、烷基硫基、氨基和Y；其中Y选自烷基、卤素、烷氧基、烷基硫基、硝基和氰基；n为0到3的整数；R^6选自烷基、烯基、烷氧基烷基和Z；其中Z选自烷基、卤素、烷氧基、烷基硫基、硝基和氰基；p为0到3的整数。
• [EN] 5-ETHYLIMIDAROTRIAZONES<br/>[FR] 5-ETHYLIMIDAROTRIAZONES
  申请人：BAYER HEALTHCARE AG

  公开号：WO2003097645A1

  公开（公告）日：2003-11-27

  The invention relates to novel 5-ethyl-imidazotriazinones, processes for their preparation and their use in medicaments, esp. for the treatment and/or prophylaxis of inflammatory processes and/or immune diseases.

  这项发明涉及新型5-乙基咪唑三唑酮，其制备方法以及它们在药物中的应用，特别是用于治疗和/或预防炎症过程和/或免疫性疾病。