[Cu(μ2-Hsucm-κO:κO':κO'')(terpy)]n(ClO4)n | 1233520-74-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Cu(μ2-Hsucm-κO:κO':κO'')(terpy)]n(ClO4)n
• 英文别名: [Cu(succinamate)(2,2':6',2''-terpyridine)]n(ClO4)n
• CAS: 1233520-74-5
• 化学式: C₁₉H₁₇CuN₄O₃*ClO₄
• 分子量: 512.366
• InChiKey: AJRCKACLRGAJSK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  α,α,α-三联吡啶 、 copper(II) perchlorate hexahydrate 、 丁酰胺酸 在 LiOH*H₂O 作用下， 以 甲醇 为溶剂， 以55%的产率得到[Cu(μ2-Hsucm-κO:κO':κO'')(terpy)]n(ClO4)n
  参考文献：
  名称：

  Complexes derived from the copper(II)/succinamic acid/N,N′,N″-chelate tertiary reaction systems: Synthesis, structural and spectroscopic studies

  摘要：

  The use of succinamic acid (H(2)sucm) in Cu-II/N,N',N ''-donor [2,2':6',2 ''-terpyridine (terpy), 2,6-bis(3,5-dimethylpyrazol-1-yl)pyridine (dmbppy)] reaction mixtures yielded compounds [Cu(Hsucm)(terpy)](n)(ClO4)(n) (1), [Cu(Hsucm)(terpy)(MeOH)](ClO4) (2), [Cu-2(Hsucm)(2)(terpy)(2)](ClO4)(2) (3), [Cu(ClO4)(2)(terpy)(MeOH)] (4), [Cu(Hsucm)(dmbppy)](n)(NO3)(n)center dot 3nH(2)O (5.3nH(2)O), and [CuCl2(dmbppy)]center dot H2O (6 center dot H2O). The succinamate(-1) ligand exists in four different coordination modes in the structures of 1-3 and 5, i.e., the mu(2)-kappa O:kappa O':kappa O '' in 1 and 5 which involves asymmetric chelating coordination of the carboxylato group and ligation of the amide O-atom leading to 1D coordination polymers, the mu(2)-kappa O-2:kappa O' in 3 which involves asymmetric chelating and bridging coordination of the carboxylato group, and the asymmetric chelating mode in 2. The primary amide group, either coordinated in 1 and 5, or uncoordinated in 2 and 3, participate in hydrogen bonding interactions, leading to interesting crystal structures. Characteristic IR bands of the complexes are discussed in terms of the known structures and the coordination modes of the Hsucm(-) ligands. The thermal decomposition of complex 5 center dot 3nH(2)O was monitored by TG/DTG and DTA measurements. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.03.003