Trichlororhodium;1,4,7-trithionane | 133313-40-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Trichlororhodium;1,4,7-trithionane
• 英文别名: trichlororhodium;1,4,7-trithionane
• CAS: 133313-40-3
• 化学式: C₆H₁₂Cl₃RhS₃
• 分子量: 389.624
• InChiKey: HYZCTQCCYHQUSA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  4.27
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  75.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  carbonyl(triphenylphosphine)(1,4,7-trithiacyclononane-S,S',S'')rhodium hexafluorophosphate 在 CH₂Cl₂ 作用下， 以 二氯甲烷 为溶剂， 以0%的产率得到Trichlororhodium;1,4,7-trithionane
  参考文献：
  名称：

  1,4,7-三硫代环壬烷（[9] aneS 3）的阳离子半三明治铑（I）配合物的合成。[Rh（[9] aneS 3）（C 2 H 4）2 ] PF 6，[Rh（[9] aneS 3）（C 8 H 12）] BF 4和[Rh（[9] ] aneS 3）（C 4 H 6）] PF 6 ·0.25OEt 2

  摘要：

  [Rh 2 L 2 L′ 2 Cl 2 ] {L，L′＝ C 2 H 4，½cod或½nbd的反应；L ＝ C 2 H 4，L′＝ PPr i 3或P（C 6 H 11）3；cod =环辛-1,5-二烯，nbd =降冰片二烯（bicyclo [2.2.1] hepta-2,5-diene）}，其中2摩尔当量的1,4,7-ththiacyclononane（[9] aneS 3）在293 K下存在NaBF 4或NH 4 PF 6，或处理[Rh（C 4 H 6）2 Cl]或[Rh（CO）Cl（PPh 3））2 ]与1摩尔当量的[9] aneS 3和NH 4 PF 6得到[Rh（[9] aneS 3）L（L'）] X [L，L'= C 2 H 4，½cod，½nbd或½C 4 ħ 6 ; L = C 2 H 4，L'= PPr i 3，P（C 6 H 11）3；L = CO，L'= PPh 3；X

  DOI：

  10.1039/dt9940002197

文献信息

• Interaction with calf-thymus DNA and photoinduced cleavage of pBR322 by rhodium(III) and iridium(III) complexes containing crown thioether ligands
  作者：Jisook Kim、Ashley D. Cardenal、Hendrik J. Greve、Weinan Chen、Hitesh Vashi、Gregory Grant、Titus V. Albu

  DOI：10.1016/j.ica.2017.10.005

  日期：2018.1

  calf-thymus (CT) DNA by a series of thioether metal complexes. The complexes of interest are rhodium and iridium complexes containing thiacrown ligands 1,4,7-trithiacyclononane (9S3) and 1-oxa-4,7-dithiacyclononane (9S2O), and the complexes are abbreviated as [Rh(9S3)Cl3], [Rh(9S2O)Cl3], and [Ir(9S3)Cl3]. In the nicking assay, pBR322 was treated with each complex and irradiated at 254 and 350 nm, respectively

  摘要在本报告中，我们研究了一系列硫醚金属配合物对质粒pBR322的光诱导裂解以及与小牛胸腺（CT）DNA的结合相互作用的研究。感兴趣的配合物是含有硫杂冠配体1,4,7-三硫代环壬烷（9S3）和1-oxa-4,7-二硫代环壬烷（9S2O）的铑和铱配合物，该配合物缩写为[Rh（9S3）Cl3]， [Rh（9S2O）Cl3]和[Ir（9S3）Cl3]。在切口试验中，pBR322用每种复合物处理，并分别在浓度和时间依赖性研究中分别在254和350 nm处辐照。刻痕试验表明，在254 nm辐射下，[Rh（9S3）Cl3]和[Rh（9S2O）Cl3]裂解pBR322有效形成刻痕形式，而[Ir（9S3）Cl3]效率最低。对于350 nm的辐射，观察到了类似的趋势，[Rh（9S3）Cl3]是最有效的化合物，但其效率低于254 nm。还进行了溴化乙锭置换试验，通过用研究的复合物滴定CT-DNA和EB的预平衡
• Synthesis, structure and reactivity of cationic rhodium(<scp>I</scp>) and iridium(<scp>I</scp>) thioether crowns: structures of [M([9]aneS₃)(cod)]⁺(M = Rh, Ir; cod = cycloocta-1,5-diene) and [Rh([9]aneS₃)(C₂H₄)₂]⁺([9]aneS₃= 1,4,7-trithiacyclononane)
  作者：Alexander J. Blake、Malcolm A. Halcrow、Martin Schröder

  DOI：10.1039/c39910000253

  日期：——

  Reaction of MI species with [9]aneS3 affords half-sandwich complexes including [M([9]aneS3)(cod)]+, [M([9]aneS3)(coe)2]+(M = Rh, Ir; coe = cyclooctene), [(Rh([9]aneS3)(C2H4)2]+, [Rh([9]aneS3)(C2H4)(PR3)]+(R = Ph, cyclohexyl), [Rh([9]aneS3)(CO)(PPh3)]+ and [Rh([9]aneS3)(tcne)(NCMe)]+; crystal structure determinations of [M([9]aneS3)(cod)]+(M = Rh, Ir) and [Rh([9]aneS3)(C2H4)2]+ confirm these complexes to be five-coordinate, and the latter species reacts with C–X (X = halide) bonds.

  MI 物种与 [9]aneS3 反应生成半三明治复合物，包括 [M([9]aneS3)(cod)]+、[M([9]aneS3)(coe)2]+（M = Rh、Ir；coe = 环辛烯）、[(Rh([9]aneS3)(C2H4)2]+、[Rh([9]aneS3)(C2H4)(PR3)]+（R = Ph、环己基）、[Rh([9]aneS3)(CO)(PPh3)]+ 和 [Rh([9]aneS3)(tcne)(NCMe)]+；M([9]aneS3)(cod)]+（M = Rh、Ir）和[Rh([9]aneS3)(C2H4)2]+ 的晶体结构测定证实这些配合物为五配位，后一种配合物与 C-X（X = 卤化物）键发生反应。
• Novel single-site catalysts containing a platinum group metal and a macrocyclic sulfur ligand for ethylene polymerization
  作者：Sari Timonen、Tuula T. Pakkanen、Tapani A. Pakkanen

  DOI：10.1016/1381-1169(96)00201-4

  日期：1996.9

  The reactions of RhCl3 . 3H(2)O and PtCl4 with 1,4,7-trithiacyclononane in ethanol lead to the formation of (S-3-ethano-9)RhCl3 and (S-3-ethano-9)PtCl4, respectively. The complexes catalyzed polymerization of ethylene in pentane in the presence of methylalumoxane (MAO) at 70 degrees C and at ethylene pressure of 10 bar. The obtained polyethylenes had an averaged molecular weight of M(w) = 272,000 ((S-3-ethano-9)RhCl3) and 901,000 ((S-3-ethano-9)PtCl4) and narrow molecular weight distributions of M(w)/M(n) = 2.95 (M(n) = 92,000) ((S-3-ethano-9)RhCl3) and M(w)/M(n) = 4.0 (M(n) = 226,000) ((S-3-ethano-9)PtCl4). On the basis of the narrow molecular weight distribution the catalysts can be considered as single-site catalysts.
• Synthesis of cationic half-sandwich rhodium(<scp>I</scp>) complexes of 1,4,7-trithiacyclononane ([9]aneS₃). The single-crystal structures of [Rh([9]aneS₃)(C₂H₄)₂]PF₆, [Rh([9]aneS₃)(C₈H₁₂)]BF₄and [Rh([9]aneS₃)(C₄H₆)]PF₆·0.25OEt₂
  作者：Alexander J. Blake、Robert O. Gould、Malcolm A. Halcrow、Martin Schröder

  DOI：10.1039/dt9940002197

  日期：——

  β= 96.844(18)° and Z= 8. The structure shows a quasi-square-pyramidal complex cation. Treatment of [Rh2(CO)4Cl2] with [9]aneS3 and NH4PF6 yielded the dimeric complex [Rh2([9]aneS3)2(µ-CO)3][PF6]2. Reaction of [Rh([9]aneS3)(C2H4)L]+[L = C2H4 or P(C6H11)3] with halogenated substrates afforded insoluble [Rh([9]aneS3)X3](X = Cl or I), while no reaction was observed with C6H6 or SiEt3H. Spectroscopic, structural

  [Rh 2 L 2 L′ 2 Cl 2 ] L，L′＝ C 2 H 4，½cod或½nbd的反应；L ＝ C 2 H 4，L′＝ PPr i 3或P（C 6 H 11）3；cod =环辛-1,5-二烯，nbd =降冰片二烯（bicyclo [2.2.1] hepta-2,5-diene）}，其中2摩尔当量的1,4,7-ththiacyclononane（[9] aneS 3）在293 K下存在NaBF 4或NH 4 PF 6，或处理[Rh（C 4 H 6）2 Cl]或[Rh（CO）Cl（PPh 3））2 ]与1摩尔当量的[9] aneS 3和NH 4 PF 6得到[Rh（[9] aneS 3）L（L'）] X [L，L'= C 2 H 4，½cod，½nbd或½C 4 ħ 6 ; L = C 2 H 4，L'= PPr i 3，P（C 6 H 11）3；L = CO，L'= PPh 3；X