2-(prop-2-ene-1-sulfonyl)-pyrrole | 66785-87-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 2-(prop-2-ene-1-sulfonyl)-pyrrole
• 英文别名: 2-prop-2-enylsulfonyl-1H-pyrrole
• CAS: 66785-87-3
• 化学式: C₇H₉NO₂S
• 分子量: 171.22
• InChiKey: DXBUADNLRAEZGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  58.3
• 氢给体数：
  1
• 氢受体数：
  2

文献信息

• Herbicidal pyrrole sulfonamides
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0039239A2

  公开（公告）日：1981-11-04

  Compounds of the formula:- or wherein R1 is H, alkyl, NO2, CN, C02H, or various acyl or ester groups; R2 is H or alkyl; R3 is H, alkyl, Cl or Br; R4 is H, alkyl, cyanoethyl, cycloalkyl, benzyl, substituted phenyl, or various acyl, ester or amide groups; R9 is H, CH3 or OCH3; R10 is wherein X is CH3 or OCH3; Y and Y' are H, Cl or various organic groups; Z is CH, N, CCH3, CCH2CH3, CCH2CH2CI, CCI, CBr or CF; and their agriculturally suitable salts; exhibit herbicidal activity. Some can be used as plant growth regulants. The compounds can be formulated for use in conventional manner. The compounds (lc) and (lb) can be made by reacting The compounds offormula (III) are also novel; these may be made by reacting chlorosulfonyl isocyanate with the appropriate heterocyclic amine R9R10NH.

  式中的化合物 或 其中 R1 是 H、烷基、NO2、CN、C02H 或各种酰基或酯基； R2 是 H 或烷基 R3 是 H、烷基、Cl 或 Br； R4 是 H、烷基、氰乙基、环烷基、苄基、取代苯基或各种酰基、酯基或酰胺基； R9 是 H、CH3 或 O ； R10 是 其中 X 是 或 O ； Y 和 Y' 是 H、Cl 或各种有机基团； Z 是 CH、N、C 、CCH2 、CCH2CH2CI、CCI、CBr 或 CF； 以及它们在农业上适用的盐；具有除草活性。有些可用作植物生长调节剂。这些化合物可按常规方法配制使用。 化合物（lc）和（lb）可通过以下反应制得 式(III)化合物也很新颖；这些化合物可通过氯磺酰异氰酸酯与适当的杂环胺 R9R10NH 反应制得。
• 3-[alpha-(3,5-di-t-butyl-4-hydroxyphenyl)-alkanoyl]pyrroles, their de-oxy analogs, and therapeutic uses thereof
  申请人：SYNTEX (U.S.A.) INC.

  公开号：EP0269981A1

  公开（公告）日：1988-06-08

  3-[ω-(3,5-Di-t-butyl-4-hydroxyphenyl)alkanoyl]­pyrroles and their de-oxy analogs, for example, 3-(3,5-di-t-butyl-4-hydroxybenzyl)pyrrole, 2-chloro-4-(3,5-di-t-butyl-4-hydroxybenzoyl)pyrrole, 3-(3,5-di-t-butyl-4-hydroxybenzoyl)pyrrole and 3-[2-(3,5-di-t-butyl-4-hydroxyphenyl)-1-oxoethyl]pyrrole, are useful for the treatment of psoriasis or other allergic conditions such as conjunctivitis, bronchial asthma and inflammatory bronchial diseases; inflammatory bowel disease; inflammatory diseases; as analgesic and antipyretic agents; in bone diseases such as osteoporosis, periodontitis, tumor-related hypercalcemia, osteopetrosis, and Paget's Disease; and in ischemic heart disease including myocardial ischemia and myocardial infarction.

  3-[ω-(3,5-二叔丁基-4-羟基苯基)烷酰基]吡咯及其脱氧类似物，例如 3-(3,5-二叔丁基-4-羟基苄基)吡咯、2-氯-4-(3,5-二叔丁基-4-羟基苯甲酰基)吡咯、3-(3、2-(3,5-二叔丁基-4-羟基苯甲酰基)吡咯、3-(3,5-二叔丁基-4-羟基苯甲酰基)吡咯和 3-[2-(3,5-二叔丁基-4-羟基苯基)-1-氧代乙基]吡咯，可用于治疗牛皮癣或其他过敏性疾病，如结膜炎、支气管哮喘和支气管炎性疾病；炎症性肠病；炎症性疾病；镇痛剂和解热剂；骨病，如骨质疏松症、牙周炎、肿瘤相关高钙血症、骨质硬化症和 Paget 病；以及缺血性心脏病，包括心肌缺血和心肌梗塞。
• GAS BARRIER COMPOSITION, COATING FILM, METHODS FOR PRODUCING THOSE, AND MULTILAYER BODY
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1894971A1

  公开（公告）日：2008-03-05

  A composition having gas-barrier properties, which can produce a resin film having gas-barrier properties under high humidity conditions and high abrasion resistance, and a coating film formed by thermally treating a film-like product of the composition having gas-barrier properties and a method for producing the same are provided. A composition having gas-barrier properties, comprising a water-soluble polymer having hydroxyl group (A), a water-soluble polymer having carboxyl group (B), a metal alkoxide and/or a hydrolysis condensate thereof (C), and an esterification catalyst (E), such that the weight ratio of the component (A) and the component (B) is 97/3 to 3/97, and the component (C) is contained in an amount ranging from 1 part by weight to 400 parts by weight, while the component (E) is contained in an amount ranging from 0.01 part by weight to 100 parts by weight, relative to 100 parts by weight of a mixture of the component (A) and the component (B); and a coating film obtained by thermally treating a film-like product of the composition having gas-barrier properties.

  本发明提供了一种具有气体阻隔性的组合物，该组合物可在高湿度条件下生成具有气体阻隔性和高耐磨性的树脂薄膜，还提供了一种通过热处理具有气体阻隔性的组合物的膜状产物而形成的涂膜以及生产该涂膜的方法。一种具有气体阻隔性能的组合物，由具有羟基的水溶性聚合物（A）、具有羧基的水溶性聚合物（B）、金属烷氧基和/或其水解缩合物（C）以及酯化催化剂（E）组成，其中组分（A）和组分（B）的重量比为 97/3 至 3/97，组分（C）的含量范围为 1 份（重量）至 400 份（重量），而组分（E）的含量范围为 0.01份（重量）至100份（重量），相对于100份（重量）的组分(A)和组分(B)混合物；以及通过热处理具有气体阻隔性能的该组合物的膜状产品而获得的涂膜。
• GAS BARRIER COMPOSITION, COATING FILM, METHOD FOR PRODUCING THE GAS BARRIER COMPOSITION, METHOD FOR PRODUCING THE COATING FILM, AND MULTILAYER BODY
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2277954A1

  公开（公告）日：2011-01-26

  Disclosed is a composition having gas-barrier properties, comprising: a water-soluble polymer (X), a metal alkoxide and/or a hydrolysis condensate thereof (C) and an esterification catalyst (E), wherein said water-soluble polymer (X) contains at least one of (i) a mixture of a water-soluble polymer having hydroxyl groups (A) and a water-soluble polymer having carboxyl groups (B), and (ii) a water-soluble polymer having a hydroxyl group and a carboxyl group (AB) and said component (C) is contained in an amount of not less than 460 parts by weight and not more than 2, 700 parts by weight, and said component (E) is contained in an amount of not less than 0.01 part by weight and not more than 100 parts by weight, relative to 100 parts by weight of said water-soluble polymer (X).

  公开了一种具有气体阻隔性能的组合物，该组合物包括水溶性聚合物 (X)、金属烷氧基和/或其水解缩合物 (C) 以及酯化催化剂 (E)，其中所述水溶性聚合物 (X) 包含以下至少一种：(i) 具有羟基的水溶性聚合物 (A) 和具有羧基的水溶性聚合物 (B) 的混合物、(ii) 具有羟基和羧基的水溶性聚合物(AB)，所述组分(C)的含量以重量份数计不少于 460 份但不多于 2,700 份，所述组分(E)的含量以重量份数计不少于 0.相对于 100 重量份的所述水溶性聚合物 (X) 而言，所述组分 (E) 的含量不低于 0.01 重量份但不超过 100 重量份。
• Alkoxymethylation of pyrroles to produce pesticides
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0669318B1

  公开（公告）日：1998-07-15