(dimethylphosphinodithioato)triphenylgermanium | 170307-89-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (dimethylphosphinodithioato)triphenylgermanium
• 英文别名: dimethyl-sulfanylidene-triphenylgermylsulfanyl-λ5-phosphane
• CAS: 170307-89-8
• 化学式: C₂₀H₂₁GePS₂
• 分子量: 429.082
• InChiKey: NMIATXUGHDEMKV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.04
• 重原子数：
  24.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  sodium dimethylphosphinodithioate dihydrate 、 三苯基氯化锗 以 苯 为溶剂， 以74%的产率得到(dimethylphosphinodithioato)triphenylgermanium
  参考文献：
  名称：

  Synthesis and characterization of triphenylgermanium(IV) diorganophosphinodithioates: Crystal and molecular structures of Ph3GeS(S)PR2 (R  Me, Ph)

  摘要：

  The first triphenylgermanium diorganophosphinodithioates, Ph(3)GeS(S)PR(2) (R = Me, Et, Ph), were synthesized by metathesis reactions between Ph(3)GeCl and the ammonium or sodium salt of the corresponding dithio acid. The compounds were characterized by IR, MS and multinuclear NMR (H-1, C-13, P-31) spectroscopy. The solid state molecular structures of Ph(3)GeS(S)PR(2) (R = Me, Ph) were determined by X-ray diffractometry. Both compounds are monomeric, with the monometallic monoconnective (monodentate) 1,1-dithio ligand and slightly distorted, tetrahedral coordination geometry at the germanium atom.

  DOI：

  10.1016/0277-5387(94)00495-z