hydrido(trimethylphosphane)tris(2,6-diisopropylphenyloxy)titanium(IV) | 168000-42-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: hydrido(trimethylphosphane)tris(2,6-diisopropylphenyloxy)titanium(IV)
• CAS: 168000-42-8
• 化学式: C₃₉H₆₁O₃PTi
• 分子量: 656.765
• InChiKey: RMGGTGUTSCLZKX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  三甲基(苯乙炔基)锡 、 hydrido(trimethylphosphane)tris(2,6-diisopropylphenyloxy)titanium(IV) 以 氘代苯 为溶剂， 生成 tris(2,6-diisopropylphenoxy)(cis-1-(trimethylstannyl)-2-phenylethenyl)titanium
  参考文献：
  名称：

  Nöth, Heinrich; Schmidt, Martin, Organometallics, 1995, vol. 14, # 10, p. 4601 - 4610

  摘要：

  DOI：
• 作为产物：
  描述：

  锂硼氢 、 三甲基膦 、 tris(2,6-diisopropylphenolato)titanium(IV) chloride 以 乙醚 、 正己烷 为溶剂， 以25%的产率得到hydrido(trimethylphosphane)tris(2,6-diisopropylphenyloxy)titanium(IV)
  参考文献：
  名称：

  Nöth, Heinrich; Schmidt, Martin, Organometallics, 1995, vol. 14, # 10, p. 4601 - 4610

  摘要：

  DOI：

文献信息

• Tris(2,6‐diisopropylphenolato)titanium(IV) Dihydridodiorganylborates: Synthesis and Structures
  作者：Jörg Knizek、Heinrich Nöth

  DOI：10.1002/ejic.201001108

  日期：2011.4

  The reactions of tris(2,6-diisopropylphenolato)titanium(IV) chloride with alkali-metal dihydridodiorganylborates M(H2BR2) (M = Li, K; R = Me, C6H11, CMe3; BR2 = BC5H10, BC8H14) led to the corresponding titanium dihydridodiorganylborates. However, in almost all cases byproducts such as (2,6-diisopropylphenolato)diorganylboranes, triorganylboranes, diorganylboranes, diborane and tetrakis(2,6-diisopr

  三（2,6-二异丙基苯酚）氯化钛（IV）与碱金属二氢二有机基硼酸盐 M（H2BR2）（M = Li，K；R = Me，C6H11，CMe3；BR2 = BC5H10，BC8H14）的反应导致了相应的二氢二有机硼酸钛。然而，在几乎所有情况下，也会产生副产物，例如（2,6-二异丙基苯酚）二有机基硼烷、三有机基硼烷、二有机基硼烷、乙硼烷和四（2,6-二异丙基苯酚）钛 (IV)。(2,6-iPr2C6H3O)3Ti(H2BR2) 化合物也是甲基三（2,6-二异丙基苯酚）钛与儿茶酚硼烷相互作用的产物。除了生成三（2,6-二异丙基苯酚）儿茶酚硼钛（IV）外，还生成了 B-甲基儿茶酚硼烷。二氢-9-环辛基硼酸钾与 2,6-双（2，2-二叔丁基-2-羟乙基）吡啶二氯化钛（LTiCl2）生成复合物LTi（H2BC8H14）2。与 (2,6-iPr2C6H3O)3TiH2BC8H14 和相应的二氢化双（环己基）硼酸钛相比，该化合物没有表现出激动的
• Reaction of a monomeric titanium hydride with dioxygen does not produce a stable titanium hydroperoxide
  作者：Brian J. Boro、Raymond Lansing、Karen I. Goldberg、Richard A. Kemp

  DOI：10.1016/j.inoche.2011.01.014

  日期：2011.4

  The reaction of gaseous O-2 under mild conditions with the monomeric titanium hydride (DIPP-O)(3)TiH(PMe3) (DIPP = 2,6-diisopropylphenyl), initially prepared by With, results in loss of the titanium hydride moiety with the isolation of (DIPP-O)(3)Ti-O-Ti(O-DIPP)(3), a dinuclear species containing a mu(2)-bridging oxo atom. This species has been characterized spectroscopically as well as by single crystal X-ray diffraction. The structure is a surprisingly rare example of a homoleptic aryloxide derivative of the Ti-O-Ti framework. Speculation upon the route used to form (DIPP-O)(3)Ti-O-Ti(O-DIPP)(3) is also presented. (C) 2011 Elsevier B.V. All rights reserved.