4-[[3-[[3-(Anthracen-9-ylmethoxy)-5-[[3,5-bis[(4-carboxyphenyl)methoxy]phenyl]methoxy]phenoxy]methyl]-5-[(4-carboxyphenyl)methoxy]phenoxy]methyl]benzoic acid | 1383714-99-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 4-[[3-[[3-(Anthracen-9-ylmethoxy)-5-[[3,5-bis[(4-carboxyphenyl)methoxy]phenyl]methoxy]phenoxy]methyl]-5-[(4-carboxyphenyl)methoxy]phenoxy]methyl]benzoic acid
• CAS: 1383714-99-5
• 化学式: C₆₇H₅₂O₁₅
• 分子量: 1097.14
• InChiKey: CNPBKKXMACIBPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.8
• 重原子数：
  82
• 可旋转键数：
  25
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  214
• 氢给体数：
  4
• 氢受体数：
  15

反应信息

• 作为产物：
  描述：

  Methyl 4-[[3-[[3-(anthracen-9-ylmethoxy)-5-[[3,5-bis[(4-methoxycarbonylphenyl)methoxy]phenyl]methoxy]phenoxy]methyl]-5-[(4-methoxycarbonylphenyl)methoxy]phenoxy]methyl]benzoate 在 potassium hydroxide 、 盐酸 作用下， 以 四氢呋喃 、 甲醇 、 水 为溶剂， 反应 8.0h， 以78%的产率得到4-[[3-[[3-(Anthracen-9-ylmethoxy)-5-[[3,5-bis[(4-carboxyphenyl)methoxy]phenyl]methoxy]phenoxy]methyl]-5-[(4-carboxyphenyl)methoxy]phenoxy]methyl]benzoic acid
  参考文献：
  名称：

  Observation of anthracene excimer fluorescence at very low concentrations utilizing dendritic structures

  摘要：

  We prepared water-soluble anthracene-cored poly(aryl ether) dendrimers wG1 and wG2, together with lipophilic dendrimers G1 and G2, and examined their photochemical properties. Water-soluble dendrimers wG1 and wG2 produced excimer emissions peaking at 463 nm and 447 nm, respectively, in water at a concentration of 10(-5) M, indicating that these dendrimers could form aggregates under highly diluted conditions. The results presented here are the first clear report of the observations of the excimer emission of anthracene in very low fluid solutions in which appropriate substituents were introduced. (C) 2011 Published by Elsevier B.V.

  DOI：

  10.1016/j.jphotochem.2011.07.008