(2,4,6-tri-tert-butylphenyl)difluorostibine | 847144-44-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2,4,6-tri-tert-butylphenyl)difluorostibine
• 英文别名: 2,4,6-tri-tert-butylphenyldifluorostibane；2,4,6-tri-tert-butylphenyl*SbF₂；Mes*SbF₂；2,4,6-tri-tert-butylphenyl-SbF2；difluoro-(2,4,6-tritert-butylphenyl)stibane
• CAS: 847144-44-9
• 化学式: C₁₈H₂₉F₂Sb
• 分子量: 405.175
• InChiKey: WBMACFMKDAUNNN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.21
• 重原子数：
  21.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  (2,4,6-tri-tert-butylphenyl)difluorostibine 、 2,4,6-三叔丁基苯酚 在 n-BuLi 作用下， 以 四氢呋喃 为溶剂， 以55%的产率得到2,4,6-tri-tert-butylphenyl-Sb(O-2,4,6-tri-tert-butylphenyl)F
  参考文献：
  名称：

  Chlorophosphaalkenyl- and chloroalkenylstibanes

  摘要：

  Mono-, bis- and tris( chlorophosphaalkenyl) stibanes have been obtained from Mes*P=C( SiMe3) Li ( Mes* = 2,4,6-tri-tert-butylphenyl) or from the phosphaalkene carbenoid Mes* P=C( X) Li ( X = Cl) and SbF3, Mes*Sb( OMes*) F or Mes*SbF2. Bis[ chloroalkenyl] stibanes [ R2C=C(Cl)](2)SbCl (R2C =fluorenylidene and 2,7-di-tert-butylfluorenylidene) have also been obtained from R2C=C( Cl) Li and SbCl3. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.04.012
• 作为产物：
  描述：

  1-溴-2,4,6-三叔丁基苯 在 n-BuLi 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 (2,4,6-tri-tert-butylphenyl)difluorostibine
  参考文献：
  名称：

  Chlorophosphaalkenyl- and chloroalkenylstibanes

  摘要：

  Mono-, bis- and tris( chlorophosphaalkenyl) stibanes have been obtained from Mes*P=C( SiMe3) Li ( Mes* = 2,4,6-tri-tert-butylphenyl) or from the phosphaalkene carbenoid Mes* P=C( X) Li ( X = Cl) and SbF3, Mes*Sb( OMes*) F or Mes*SbF2. Bis[ chloroalkenyl] stibanes [ R2C=C(Cl)](2)SbCl (R2C =fluorenylidene and 2,7-di-tert-butylfluorenylidene) have also been obtained from R2C=C( Cl) Li and SbCl3. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.04.012

文献信息

• The first evidence for a transient stibaallene ArSbCCR2
  作者：Lise Baiget、Henri Ranaivonjatovo、Jean Escudié、Gabriela Cretiu Nemes、Ioan Silaghi-Dumitrescu、Luminita Silaghi-Dumitrescu

  DOI：10.1016/j.jorganchem.2004.09.022

  日期：2005.1

  Dechlorofluorination of ArSb(F)-C(Cl) = CR2 (CR2 = fluorenylidene, Ar = 2,4,6-tri-tert-butylphenyl) by tert-butyllithium afforded a 3,4-bis(fluorenylidene)-1,2-distibacyclobutane. The formation of the latter probably involves the transient stibaallene ArSb = C = CR2 followed by a head-to-head dimerization via two Sb = C double bonds. Molecular orbital calculations at the ab initio and DFT levels support the head-to-head dimerization of ArSb = C = CR2 with the formation of a 1,2-distibacyclobutane. (C) 2004 Elsevier B.V. All rights reserved.
• Stibasilene Sb═Si and Its Lighter Homologues: A Comparative Study
  作者：Vladimir Ya. Lee、Shinji Aoki、Manami Kawai、Takahiko Meguro、Akira Sekiguchi

  DOI：10.1021/ja5026084

  日期：2014.4.30

  The multiply bonded derivatives of the heavier main group elements are among the most challenging targets for synthetic pursuits. Those of them featuring a double bond between the silicon and group 15 element are represented mostly by the silaimines -N=Si< and phosphasilenes -P=Si< with a very few examples of arsasilenes -As=Si<. In this contribution, we report on the synthesis and structural elucidation of the first stable stibasilene and novel phosphasilene and arsasilene derivatives, featuring an identical substitution pattern. A systematic comparison within the series phosphasilene-arsasilene-stibasilene is made on the basis of their experimental and computational studies.