[(Ph3P)2Pt](5,5,16,16-tetramethyl-5,16-didehydro-5,16-disiladibenzo[a,e]naphtho[c]cyclooctene) | 198979-18-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(Ph3P)2Pt](5,5,16,16-tetramethyl-5,16-didehydro-5,16-disiladibenzo[a,e]naphtho[c]cyclooctene)
• CAS: 198979-18-9
• 化学式: C₆₂H₅₄P₂PtSi₂
• 分子量: 1112.31
• InChiKey: ACDGYWJLHCAMMH-YXEOUQEWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.35
• 重原子数：
  67.0
• 可旋转键数：
  8.0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  乙烯双(三苯基磷)铂 、 5,6,11,12-四氢二苯并[a,e]环辛四烯 、 1,2-bis(dimethylsilyl)benzene 以 not given 为溶剂， 生成 [(Ph3P)2Pt](5,5,16,16-tetramethyl-5,16-didehydro-5,16-disiladibenzo[a,e]naphtho[c]cyclooctene)
  参考文献：
  名称：

  Reactions of 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene with 1,2-C6H4(SiMe2)2Pt(PPh3)2 and Pt(CH2-CH2) (PPh3)2. x-ray structure determination of resulting double silylated compounds and platinum-alkyne complexes

  摘要：

  The platinum complex of 5,6,11,12-tetradehydrodibenzo[a,e]cyclooctene (1), [(Ph3P)(2)Pt](2)[1], was synthesized quantitatively by the reaction of 1 with Pt(CH2=CH2)(PPh3)(2). The reaction of 1 with 1,2-C6H4(SiMe2)(2)Pt(PPh3)(2) gave 5,5,10,10,15,15,20,20-octamethyl- 5,10,15,20-tetrahydro-5,10,15,20-tetrasiladibenzo[b,n]tetraphenylene ([C6H4(SiMe2)(2)](2)(C16H8)) and [(Ph3P)(2)Pt][C6H4(SiMe2)(2)-C16H8] (C6H4(SiMe2)(2)C16H8 = 5,5,16,16-tetramethyl-5,16-dihydro-10,11-didehydro-5,16-disiladibenzo[a,e]naphtho[c]cyclooctene) as well as [(Ph3P)(2)Pt](2)[1]. The central eight-membered ring of [C6H4(SiMe2)(2)](2)(C16H8) has a typical tub-shaped structure, while that of [(Ph3P)(2)Pt](2)[1] is much less folded. The structure of [(Ph3P)(2)Pt][C6H4(SiMe2)(2)C16H8] lies between those of [C6H4(SiMe2)(2)](2)(C16H8) and [(Ph3P)(2)Pt](2)[1]. Crystal data: [(Ph3P)(2)Pt](2)[1]. 2toluene, C88H68P4Pt2.2C7H8, monoclinic, P2(1)/n, a = 16.369(2), b = 30.104(6), c=17.120(3) Angstrom,beta=102.69(1)degrees, V=8230(2) Angstrom(3), Z=4. [C6H4(SiMe2)(2)](2)(C16H8), C36H40Si4, monoclinic, P2(1)/c, a=18.421(2), b=11.131(1), c=16.444(1) Angstrom,beta=94.540(4)degrees, V=3361(4) Angstrom(3), Z=4. [(Ph3P)(2)Pt][C6H4(SiMe2)(2)C16H8], C62H54P2PtSi2, triclinic, , a=13.538(2), b=17.244(4), c=12.510(3) Angstrom,alpha=111.10(2), beta=104.93(1), gamma=80.06(2)degrees, V-2622(1) Angstrom(3), Z=2. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05682-x