| 1393840-75-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• CAS: 1393840-75-9
• 化学式: C₂H₃MnN
• 分子量: 95.9905
• InChiKey: AODSNVZDYBMLCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  锰 、 乙腈 反应 1.0h， 生成 Mn←acetonitrile 、 、
  参考文献：
  名称：

  Infrared Spectra of the Complexes Os←NCCH₃, Re←NCCH₃, CH₃–ReNC, CH₂═Re(H)NC, and CH≡Re(H)₂NC and their Mn Counterparts Prepared by Reactions of Laser-Ablated Os, Re, and Mn Atoms with Acetonitrile in Excess Argon

  摘要：

  Acetonitrile forms primarily N-coordination complexes (M <- NCCH3) with Os and Re metal atoms, but these metal atoms produce exclusively methylidyne complexes (HC MH2X) in similar previous reactions with small alkanes and halomethanes. The Os complex increases on visible photolysis and dissociates partially on UV irradiation without the generation of other new products, whereas the Re complex converts to other products (CH3-ReNC, CH2=Re(H)NC, and CH Re(H)(2)NC) on photolysis. The primary formation of the N-coordination complex originates from its stability relative to that of the nitrile pi-complex in these systems. The agostic interaction in the methylidene complex is apparently insignificant, and this rare observation of a methylidyne product with Re reflects that H migration in the isocyanide system is less favorable than those in the hydride and halide analogues. Experiments with Mn gave weaker counterpart product absorptions.

  DOI：

  10.1021/om300456k