申请人:NISSAN CHEMICAL INDUSTRIES LTD.
公开号:EP0337355A2
公开(公告)日:1989-10-18
This invention is concerned with a composition to be used as an agent for aligning liquid crystals in a liquid crystal cell, wherein liquid crystal molecules are aligned with an increased pretilt angle with respect to the substrate, such composition consists essentially of a polyimide resin precursor having repeating units represented by the formula (I)
wherein R₁ denotes an organic group constituting a tetracarboxylic acid or its derivative; and R₂ represents a divalent organic group constituting a diamine; and
a precursor of a diimide compound represented by the formula (II) or (III):
wherein R₃ denotes a divalent organic group constituting a diamine; each of R₄ and R₅ represents an organic groups constituting a dicarboxylic acid containing an alkyl group having 6 to 20 carbon atoms, or its derivative,
wherein R₆ denotes an organic group constituting a tetracarboxylic acid or its derivative, and each of R₇ and R₈ represents an organic group constituting a monoamine containing an alkyl group having 6 to 20 carbon atoms.
本发明涉及一种用作液晶池中液晶排列剂的组合物,其中液晶分子相对于基底以增大的前倾角排列,这种组合物主要由具有由式(I)表示的重复单元的聚酰亚胺树脂前体组成
其中 R₁ 表示构成四羧酸或其衍生物的有机基团;R₂ 表示构成二胺的二价有机基团;以及
式 (II) 或 (III) 所代表的二亚胺化合物的前体:
其中 R₃ 表示构成二胺的二价有机基团; R₄ 和 R₅ 各自代表构成含有 6 至 20 个碳原子的烷基的二羧酸的有机基团或其衍生物、
其中 R₆ 表示构成四羧酸的有机基团或其衍生物,R₇ 和 R₈ 各代表构成含有 6 至 20 个碳原子的烷基的单胺的有机基团。