3,5-bis[(40pyridylamino)carbonyl]benzoic acid | 1194659-17-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-bis[(40pyridylamino)carbonyl]benzoic acid
• CAS: 1194659-17-0
• 化学式: C₁₉H₁₄N₄O₄
• 分子量: 362.345
• InChiKey: ZXYBWKDGNPLXEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.68
• 重原子数：
  27.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  121.28
• 氢给体数：
  3.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  3,5-bis[(40pyridylamino)carbonyl]benzoic acid 、 lead(II) acetate trihydrate 、 N,N-二甲基甲酰胺 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 生成 ([Pb(3,5-bis[(4-pyridylamino)carbonyl]benzoate)(acetate)]*DMF)n
  参考文献：
  名称：

  Sonochemical syntheses of a new nano-sized porous lead(II) coordination polymer as precursor for preparation of lead(II) oxide nanoparticles

  摘要：

  Nano-scale of a new Pb(II) coordination polymer, {[Pb(bpacb)(OAc)]center dot DMF}(n) (1); bpacbH = 3,5-bis[(4-pyridylamino)carbonyl]benzoic acid], were synthesized by a sonochemical method. The nano-material was characterized by scanning electron microscopy, X-ray powder diffraction (XRD), H-1, C-13 NMR, IR spectroscopy and elemental analyses. Crystal structure of compound 1 was determined by X-ray crystallography. Calcination of the nano-sized compound 1 at 700 degrees C under air atmospheres yields PbO nanoparticles. Thermal stability of nano-sized and single crystalline samples of compound 1 were studied and compared with each other. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.07.041