2-(2,6 dichloroanilino)-1,3,4-trifluoroanthraquinone | 167907-17-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2-(2,6 dichloroanilino)-1,3,4-trifluoroanthraquinone
• 英文别名: 2-(2,6-Dichloroanilino)-1,3,4-trifluoroanthracene-9,10-dione
• CAS: 167907-17-7
• 化学式: C₂₀H₈Cl₂F₃NO₂
• 分子量: 422.19
• InChiKey: BYQNZZOGYRNJEW-UHFFFAOYSA-N

物化性质

• 沸点：
  495.5±45.0 °C(Predicted)
• 密度：
  1.613±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,2,3,4-tetrafluoro-9,10-anthraquinone 、 2,6-二氯苯胺 反应 8.0h， 以to give rise to 1.39 g of 2-(2,6-dichloroanilino)-1,3,4-trifluoroanthraquinone (Dye 10') (yield 46.1 mol %) and 0.78 g of 2,3-bis(2,6-dichloroanilino)-1,4-difluoroanthraquinone (Dye 25') (yield 19.4 mol %)的产率得到2-(2,6 dichloroanilino)-1,3,4-trifluoroanthraquinone
  参考文献：
  名称：

  Color filter grade photosensitive resin coloring composition and color

  摘要：

  一种用于彩色滤光片的光敏树脂着色组合物，包含树脂和染料。该染料由以下类别中选择的一种成员制造而成：(A)+(B)组合，(A)+(C)组合，(B)+(C)组合和(A)+(B)+(C)组合，其中(A)代表喹嗪染料，(B)代表蒽醌染料，(C)代表酞菁染料。

  公开号：

  US05968688A1

文献信息

• Color filter grade photosensitive resin coloring composition and color
  申请人：Nippon Shokubai Co., Ltd.

  公开号：US05968688A1

  公开（公告）日：1999-10-19

  A photosensitive resin coloring composition for use in a color filter containing a resin and a dye. The dye is manufactured with one member selected from the class consisting of a combination of (A)+(B) groups, a combination of (A)+(C) groups, a combination of (B)+(C) groups, and a combination of (A)+(B)+(C) groups, wherein (A) represents a group of quinizarine compounds, (B) represents a group of anthraquinone compounds, and (C) represents a group of phthalocyanine compounds.

  一种用于彩色滤光片的光敏树脂着色组合物，包含树脂和染料。该染料由以下类别中选择的一种成员制造而成：(A)+(B)组合，(A)+(C)组合，(B)+(C)组合和(A)+(B)+(C)组合，其中(A)代表喹嗪染料，(B)代表蒽醌染料，(C)代表酞菁染料。
• Color filter grade photosensitive resin coloring composition, and color filter using the same
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0833203A1

  公开（公告）日：1998-04-01

  A photosensitive resin coloring composition for use in a color filter containing a resin and a dye which is a material for the formation of a colored layer of the color filter, characterized in that the dye is manufactured with one member selected from the class consisting of a (C) group alone (which includes only phthalocyanine compounds represented by the formula (1) below and having one to eight unsubstituted or substituted alkoxy group(s) and/or unsubstituted or substituted phenoxy group(s) substituted at the 2, 3, 6, 7, 10, 11, 14 and 15 positions thereof), a combination of (A) + (B) groups, a combination of (A) + (C) groups, a combination of (B) + (C) groups, and a combination of (A) + (B) + (C) groups, wherein (A) represents a group of quinizarine compounds having a quinizarine skeleton in which one to three of the 5, 6, 7, and 8 positions and at least either of the 6 and 7 positions are each occupied by a secondary amino group and the remainders of the 5, 6, 7, and 8 positions are occupied each by at least one group selected from the class consisting of hydrogen atom, halogen atom, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted phenoxy group, an unsubstituted or substituted alkylthio group, and an unsubstituted or substituted phenylthio group, (B) represents a group anthraquinone compounds having an anthraquinone skeleton in which one to three of the 1, 2, 3, and 4 positions are occupied each by at least one group selected from the class consisting of secondary amimo group, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted phenoxy group, an unsubstituted or substituted alkylthio group, and an unsubstituted or substituted phenylthio group and the remainders of the 1, 2, 3, and 4 positions are occupied each by hydrogen atom or a halogen atom, and (C) represents a group of phthalocyanine compounds having a phthalocyanine skeleton represented by the following general formula (1) wherein M represents a divalent metal or a ligand-containing tetravalent metal in which one to eight of the 16 positions of benzene rings permitting substitution are occupied each by an unsubstituted or substituted alkoxy group and/or an unsubstituted or substituted phenoxy group and the remainders of the positions are occupied each by a halogen atom.

  一种用于彩色滤光片的光敏树脂着色组合物，含有树脂和染料，染料是形成彩色滤光片彩色层的材料，其特征在于染料是用选自以下类别的一个成员制造的：单独的(C)基团(仅包括下式(1)所代表的酞菁化合物，其具有1至8个未取代或取代的烷氧基和/或在2、(A)+(B)基团的组合、(A)+(C)基团的组合、(B)+(C)基团的组合以及(A)+(B)+(C)基团的组合、其中(A)代表一组具有喹嗪类骨架的喹嗪类化合物，其 5、6、7 和 8 位中的一至三个位以及 6 和 7 位中的至少一个位分别被仲氨基占据，而 5、6、7 和 8 位的剩余位分别被至少一个仲氨基占据、(B) 代表一组具有蒽醌骨架的蒽醌化合物，其中 1、2、3 和 4 位中的 1 至 3 位分别被至少一个选自仲氨基的基团占据、(C) 代表一组酞菁化合物，其酞菁骨架由以下通式 (1) 表示 其中 M 代表二价金属或含配体的四价金属，其中允许取代的苯环 16 个位置中的 1 至 8 个位置分别由未取代或取代的烷氧基和/或未取代或取代的苯氧基占据，其余位置分别由卤原子占据。
• OPTICAL SHEET AND OPTICAL COMPONENT
  申请人：Sumitomo Bakelite Co.Ltd.

  公开号：EP3690502A1

  公开（公告）日：2020-08-05

  An optical sheet of the present invention includes a specific wavelength absorption layer that contains a polycarbonate as a main material and a light absorbing agent that absorbs light of a specific wavelength out of light in a wavelength range of 350 nm to 740 nm, in which the polycarbonate has a viscosity average molecular weight Mv of 20,000 to 30,000. In addition, the specific wavelength absorption layer further includes an ultraviolet absorbing agent that absorbs light in a wavelength range of 100 nm to 420 nm.

  本发明的光学薄片包括一个特定波长吸收层，该吸收层包含作为主要材料的聚碳酸酯和一种光吸收剂，该光吸收剂可吸收 350 纳米至 740 纳米波长范围内特定波长的光，其中聚碳酸酯的粘度平均分子量 Mv 为 20,000 至 30,000。此外，特定波长吸收层还包括紫外线吸收剂，可吸收波长范围为 100 纳米至 420 纳米的光。
• RESIN COMPOSITION, OPTICAL LAYER, COVER MEMBER AND MOVABLE BODY
  申请人：Sumitomo Bakelite Co.Ltd.

  公开号：EP3719085A1

  公开（公告）日：2020-10-07

  A resin composition of the present invention is used for forming a second layer in an optical layer 10, contains a silicon-modified (meth)acryl resin, a urethane (meth)acrylate, and a polyfunctional (meth) acrylate, and satisfies the following condition A, in which the optical layer 10 includes a first layer (base material layer 1) containing a resin material and a visible light absorber and the second layer (protective layer 2) protecting the first layer. Condition A: In a case where the second layer is formed on a base material, a coating film of a mixed solvent containing a petroleum-based solvent at a proportion equal to or higher than 45 wt% is formed on the second layer and left as it is, and then the mixed solvent is removed, an adherence, which is determined by a cross-cut method, of the second layer cut in the form of a lattice with respect to the base material is equal to or higher than 95%.

  本发明的一种树脂组合物用于在光学层 10 中形成第二层，含有硅改性（甲基）丙烯酸树脂、氨基甲酸乙酯（甲基）丙烯酸酯和多官能（甲基）丙烯酸酯，并满足以下条件 A，其中光学层 10 包括含有树脂材料和可见光吸收剂的第一层（基材层 1）和保护第一层的第二层（保护层 2）。 条件 A：在第二层形成于基底材料上的情况下，在第二层上形成一层比例等于或高于 45 wt% 的含有石油基溶剂的混合溶剂的涂膜并保持原样，然后除去混合溶剂，通过横切法测定，相对于基底材料以晶格形式切割的第二层的附着力等于或高于 95%。
• RESIN COMPOSITION, MOLDED BODY, OPTICAL LAYER, COVER MEMBER AND MOVING BODY
  申请人：Sumitomo Bakelite Co.Ltd.

  公开号：EP3932669A1

  公开（公告）日：2022-01-05

  A resin composition of the present invention is used in an optical layer 10 provided with a first layer (base material layer 1) including a polycarbonate-based resin and a visible light absorber for forming the first layer. The visible light absorber includes a plurality of kinds of light absorbers, and a melting point of a first light absorber having the lowest melting point is equal to or higher than 200°C, in which a melting point of a second light absorber having the highest melting point is equal to or lower than 330°C. The resin composition is such that the viscosity at 260°C obtainable when a shear rate is 243.2 [1/sec] is equal to or more than 400 Pa·s and equal to or less than 3500 Pa·s.

  本发明的一种树脂组合物用于光学层 10 中，该光学层具有第一层（基材层 1），包括聚碳酸酯基树脂和可见光吸收剂，用于形成第一层。可见光吸收剂包括多种光吸收剂，熔点最低的第一种光吸收剂的熔点等于或高于 200°C，其中熔点最高的第二种光吸收剂的熔点等于或低于 330°C。当剪切速率为 243.2[1/秒]时，该树脂组合物在 260°C 时的粘度等于或大于 400 Pa-s，等于或小于 3500 Pa-s。