1,5-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)anthracene-9-10-dione | 111959-52-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,5-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)anthracene-9-10-dione
• 英文别名: 1,5-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)anthra-9,10-quinone；1,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]anthracene-9,10-dione
• CAS: 111959-52-5
• 化学式: C₂₈H₃₆O₁₀
• 分子量: 532.588
• InChiKey: XSSSVSGXGLTANV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  38
• 可旋转键数：
  20
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  108
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,5-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)anthracene-9-10-dione 在 sodium perchlorate 作用下， 以 四氢呋喃 为溶剂， 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Contrasting one- and two-cation binding behavior in syn- and anti-anthraquinone bibracchial podand (BiP) mono- and dianions assessed by cyclic voltammetry and electron paramagnetic resonance spectroscopy

  摘要：

  DOI：

  10.1021/ja00209a019
• 作为产物：
  描述：

  三甘醇单甲醚 、 1,5-二氯蒽醌 在 potassium hydroxide 作用下， 反应 3.0h， 以83%的产率得到1,5-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)anthracene-9-10-dione
  参考文献：
  名称：

  Anthraquinone with tailored structure for a nonaqueous metal–organic redox flow battery

  摘要：

  基于定制蒽醌结构的非水混合金属-有机氧化还原液流电池的能源效率高达82%以下，且比水氧化还原液流电池的特定放电能量密度更高，这是由于蒽醌在辅助电解质中的溶解度显著提高。

  DOI：

  10.1039/c2cc32466k

文献信息

• [EN] ION SELECTIVE MEMBRANES FOR ORGANIC ELECTROCHEMICAL PROCESSES<br/>[FR] MEMBRANES SÉLECTIVES D'IONS POUR PROCÉDÉS ÉLECTROCHIMIQUES ORGANIQUES
  申请人：UNIV VIRGINIA PATENT FOUNDATION

  公开号：WO2021188977A1

  公开（公告）日：2021-09-23

  An ion conducting polymer comprising a modified poly(phenylene oxide) is described. In an exemplary modified polymer, a portion of the monomeric units are attached to a sulfonate-substituted arylamino moiety, such as a monovalent derivative of phenoxy aniline trisulfonate (BOATS), to form a monomeric unit with a charged side chain. Ion conducting polymers can also be prepared with polyether-containing side chains. The ion conducting polymer can be used to prepare ion exchange membranes which can be used in a variety of applications, such as in non-aqueous redox flow batteries and related energy storage systems.

  本文介绍了一种离子导电聚合物，其中包括改性的聚苯醚。在一个典型的改性聚合物中，部分单体单元与磺酸取代的芳基氨基基团（例如苯氧基苯胺三磺酸的一价衍生物（BOATS））连接，形成带电侧链的单体单元。离子导电聚合物也可以用含有聚醚侧链的聚合物制备。该离子导电聚合物可用于制备离子交换膜，可用于各种应用，例如非水系氧化还原流动电池和相关的能量存储系统。
• Alkynes and poly(ethylene glycol) derivatives as nucleophiles and catalysts in substitution reactions of 1-chloroanthraquinones
  作者：Jun Ping Fang、Tianbao Lu、Hyunsook Kim、Isaura Delgado、Philippe Geoffroy、Jerry L. Atwood、George W. Gokel

  DOI：10.1021/jo00025a021

  日期：1991.12

  Two synthetically useful approaches to 1-substituted anthraquinone derivatives are reported. Application of these methods afforded the following 1-anthraquinyl ethers: n-propyl, n-butyl, n-octyl, n-nonyl, n-hexadecyl, isoamyl, allyl, 2-butenyl, (E)-2-hexenyl, (E)-2-tridecyl, benzyl, phenyl, 4-methylphenyl, 2-butynyl, 2-pentynyl, 2-hexynyl, 3-pentynyl, 3-hexynyl, 3-heptynyl, 3-nonynyl, 4-hexynyl, 4-heptynyl, 5-heptynyl, 5-octynyl, 5-nonynyl, 2-methoxyethyl, 2-(2-methoxyethoxy)ethyl, 2-[2-[2-(octadecyloxy)ethoxy]ethoxy]ethyl, 2-(methylthio)ethyl, 2-(1-piperidino)ethyl, and 2-(1-morpholino)ethyl. The results of about 100 nucleophilic substitution reactions (a number were duplicates) are presented. Most of these reactions involve either a new approach, new products, or both. Included are displacements of chloride by alkanols, alkenols, and alkynols. Of the three, only the latter afford acceptable yields of product, although lower yields are observed as the distance between hydroxyl and triple bond increases. Nucleophiles of the type RO(CH2CH2O)nOH proved remarkably effective. Alkynyl ethers and poly(oxyethylene) ethers also proved to be excellent leaving groups. Both alkynols and oligoethylene glycol monoethers were found to be catalysts for the conversion of 1-chloroanthraquinone into 1-anthraquinyl ethers. In an attempt to understand the mechanism of this reaction, solid-state structures of four anthraquinone derivatives have been obtained. These have poly(ethyleneoxy), morpholino, or alkynyl side arms.
• All-Solid-State Lithium–Sulfur Batteries Enhanced by Redox Mediators
  作者：Xin Gao、Xueli Zheng、Yuchi Tsao、Pu Zhang、Xin Xiao、Yusheng Ye、Jun Li、Yufei Yang、Rong Xu、Zhenan Bao、Yi Cui

  DOI：10.1021/jacs.1c07754

  日期：2021.11.3
• HYUNSOOK, KIM YOO;DAVIS, DAWN M.;CHEN, ZHIHONG;ECHEGOYEN, LUIS;GOKEL, GEO+, TETRAHEDRON LETT., 31,(1990) N, C. 55-58
  作者：HYUNSOOK, KIM YOO、DAVIS, DAWN M.、CHEN, ZHIHONG、ECHEGOYEN, LUIS、GOKEL, GEO+

  DOI：——

  日期：——