Ni3(OBt)6*6H2O | 1166854-61-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Ni3(OBt)6*6H2O
• 英文别名: Ni3(1-hydroxybenzotriazolato)6*6H2O
• CAS: 1166854-61-0
• 化学式: C₃₆H₃₆N₁₈Ni₃O₁₂
• 分子量: 1088.87
• InChiKey: UPBLXVROBUERRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 1-羟基苯并三唑 在 NaOH 作用下， 以 水 为溶剂， 以56%的产率得到Ni3(OBt)6*6H2O
  参考文献：
  名称：

  Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M=cobalt, nickel, silver, zinc and copper

  摘要：

  Five novel complexes, Co(OBt)(2) center dot 7H(2)O (1) (OBt = 1-hydroxybenzotriazole ion), Ni-3(OBt)(6) center dot 6H(2)O (2), [Ag(OBt)(HOBt)](n) (3), [Zn(OBt)(2)](n) (4) and [Cu-2(OBt)(4) center dot 3H(2)O](n) (5) were synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1-5 are zero-dimensional (0D), zero-dimensional, one-dimensional (1D), and three-dimensional (3D) frameworks, respectively. In particular, 3 is twin crystal; 4 possesses of double-stranded chains; 5 crystallizes in orthorhombic space group P2(1)2(1)2(1) with a helical chain in its structure. The luminescence properties and the magnetic properties of the five complexes were investigated. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.01.044