N-[3-(N-tert-butyl-N-hydroxyaminophenyl)]-(2-pyridyl)ethanimine | 844643-79-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[3-(N-tert-butyl-N-hydroxyaminophenyl)]-(2-pyridyl)ethanimine
• 英文别名: N-[3-(N-ter-butyl-N-hydroxyaminophenyl)]-(2-pyridyl)ethanimine；N-tert-butyl-N-[3-(1-pyridin-2-ylethylideneamino)phenyl]hydroxylamine
• CAS: 844643-79-4
• 化学式: C₁₇H₂₁N₃O
• 分子量: 283.373
• InChiKey: JHGBMDAEMRBJFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  48.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  nickel(II) chloride hexahydrate 、 N-[3-(N-tert-butyl-N-hydroxyaminophenyl)]-(2-pyridyl)ethanimine 以 四氢呋喃 为溶剂， 以75%的产率得到dichloro-bis-2-[3-N-ter-butyl-N-hydroxyamino-(1-pyridin-2-yl-ethyl) phenylamine]nickel(II) monohydrate
  参考文献：
  名称：

  Imino- and bis-imino-pyridines with N-ter-butyl-N-aminoxyl group: synthesis, oxidation and use as ligand towards M2+ ( Mn, Ni, Zn) and Gd3+

  摘要：

  Imino- and bis-iminopyridine ligands bearing N-ter-butylhydroxy groups were synthesized by the condensation reaction between a Al-ter-butylhydroxy substituted aniline and 2-formylpyridine, 2-acetylpyridine and 2,6-bis-acetylpyridine. The N-ter-butylaminoxy radicals obtained after oxidation using PbO2 or Ag2O were studied by EPR spectroscopy in solution. Indeed, complete decomposition was observed during isolation of these radical derivatives. The N-ter-butylhydroxy substituted ligands obtained were complexed with Mn2+, Ni2+, Zn2+ and Gd3+ salts; the obtained complexes were characterized and oxidized to give the aminoxy analogs. which were studied using IR, UV and EPR spectroscopies. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.014
• 作为产物：
  描述：

  N,N-bis(trimethylsilyl)-m-bromoaniline 在 盐酸 、 正丁基锂 、 溶剂黄146 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 74.08h， 生成 N-[3-(N-tert-butyl-N-hydroxyaminophenyl)]-(2-pyridyl)ethanimine
  参考文献：
  名称：

  Imino- and bis-imino-pyridines with N-ter-butyl-N-aminoxyl group: synthesis, oxidation and use as ligand towards M2+ ( Mn, Ni, Zn) and Gd3+

  摘要：

  Imino- and bis-iminopyridine ligands bearing N-ter-butylhydroxy groups were synthesized by the condensation reaction between a Al-ter-butylhydroxy substituted aniline and 2-formylpyridine, 2-acetylpyridine and 2,6-bis-acetylpyridine. The N-ter-butylaminoxy radicals obtained after oxidation using PbO2 or Ag2O were studied by EPR spectroscopy in solution. Indeed, complete decomposition was observed during isolation of these radical derivatives. The N-ter-butylhydroxy substituted ligands obtained were complexed with Mn2+, Ni2+, Zn2+ and Gd3+ salts; the obtained complexes were characterized and oxidized to give the aminoxy analogs. which were studied using IR, UV and EPR spectroscopies. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.014