pyridine complex of copper(II) tetradecanoate | 420788-43-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: pyridine complex of copper(II) tetradecanoate
• 英文别名: Cu2(C13H27CO2)4(py)2；Cu2(C13H27CO2)4(pyridine)2
• CAS: 420788-43-8
• 化学式: C₆₆H₁₁₈Cu₂N₂O₈
• 分子量: 1194.76
• InChiKey: QNLODUCUSSRWIS-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  pyridine complex of copper(II) tetradecanoate 以 solid 为溶剂， 生成 copper(II) tetradecanoate
  参考文献：
  名称：

  摘要：

  The compounds Cu-2(RCO2)(4) and Cu-2(RCO2)(4)py(2) [R=CH3(CH2)(n-2); n=14, 16, 18; py=pyridine] were prepared, analysed and characterized by means of DSC calorimetry, thermogravimetry and infrared spectroscopy. Generally, the pyridine complexes are unstable, losing pyridine already at room temperature. Transition from a crystalline to a liquid crystalline phase after heating was observed for all Cu-2(RCO2)(4) compounds but only for pyridine complex of Cu(II) tetradecanoate. However, the melting process was observed for all Cu(II) carboxylate complexes with pyridine. The lower thermal stability of pyridine complexes, than corresponding Cu-2(RCO2)(4) compounds can be explained by structural features.

  DOI：

  10.1023/a:1013794015995
• 作为产物：
  描述：

  吡啶 、 copper(II) tetradecanoate 以 甲醇 为溶剂， 以70%的产率得到pyridine complex of copper(II) tetradecanoate
  参考文献：
  名称：

  摘要：

  The compounds Cu-2(RCO2)(4) and Cu-2(RCO2)(4)py(2) [R=CH3(CH2)(n-2); n=14, 16, 18; py=pyridine] were prepared, analysed and characterized by means of DSC calorimetry, thermogravimetry and infrared spectroscopy. Generally, the pyridine complexes are unstable, losing pyridine already at room temperature. Transition from a crystalline to a liquid crystalline phase after heating was observed for all Cu-2(RCO2)(4) compounds but only for pyridine complex of Cu(II) tetradecanoate. However, the melting process was observed for all Cu(II) carboxylate complexes with pyridine. The lower thermal stability of pyridine complexes, than corresponding Cu-2(RCO2)(4) compounds can be explained by structural features.

  DOI：

  10.1023/a:1013794015995