4,4'-Di-(11''-dodecenyl)-2,2'-bipyridine | 140464-50-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4,4'-Di-(11''-dodecenyl)-2,2'-bipyridine
• 英文别名: 4-Dodec-11-enyl-2-(4-dodec-11-enylpyridin-2-yl)pyridine
• CAS: 140464-50-2
• 化学式: C₃₄H₅₂N₂
• 分子量: 488.8
• InChiKey: KUUPSAQBDVHWMQ-UHFFFAOYSA-N

物化性质

• 沸点：
  586.1±45.0 °C(Predicted)
• 密度：
  0.927±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  36
• 可旋转键数：
  23
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  全氟碘代丁烷 、 4,4'-Di-(11''-dodecenyl)-2,2'-bipyridine 在 copper(l) chloride 作用下， 以 C.I.酸性橙108 、 叔丁醇 为溶剂， 以62%的产率得到(E)-4,4'-Bis<12''-(F-butyl)-11''-dodecenyl>-2,2'-bipyridine
  参考文献：
  名称：

  Synthesis of new amphiphilic perfluoroalkylated bipyridines

  摘要：

  General and versatile synthetic methods have been developed for the preparation of a large variety of 2,2'-bipyridines bearing two various perfluoroalkylated side chains with an ester or a methylene junction in the 4,4'-positions, e.g., 4,4'-bis[[2"-(F-alkyl)ethenyl]alkyl]-2,2'-bipyridines, 4,4'-bis[[[(F-alkyl)alkyl]oxy]carbonyl]-2,2'-bipyridines, and 4,4'-bis[[[[2"-(F-alkyl)ethenyl]alkyl]oxy]carbonyl]-2,2'-bipyridines.

  DOI：

  10.1021/jo00037a019
• 作为产物：
  描述：

  10-十一烯-1-醇 在 吡啶 、 sodium iodide 、 lithium diisopropyl amide 作用下， 以 丙酮 为溶剂， 反应 6.0h， 生成 4,4'-Di-(11''-dodecenyl)-2,2'-bipyridine
  参考文献：
  名称：

  Synthesis of new amphiphilic perfluoroalkylated bipyridines

  摘要：

  General and versatile synthetic methods have been developed for the preparation of a large variety of 2,2'-bipyridines bearing two various perfluoroalkylated side chains with an ester or a methylene junction in the 4,4'-positions, e.g., 4,4'-bis[[2"-(F-alkyl)ethenyl]alkyl]-2,2'-bipyridines, 4,4'-bis[[[(F-alkyl)alkyl]oxy]carbonyl]-2,2'-bipyridines, and 4,4'-bis[[[[2"-(F-alkyl)ethenyl]alkyl]oxy]carbonyl]-2,2'-bipyridines.

  DOI：

  10.1021/jo00037a019

文献信息

• Synthesis and characterization of cross-linkable ruthenium complex dye and its application on dye-sensitized solar cells
  作者：Ken-Yen Liu、Chiao-Ling Hsu、Shun-Hsing Chang、Jian-Ging Chen、Kuo-Chuan Ho、King-Fu Lin

  DOI：10.1002/pola.23793

  日期：2010.1.15

  AbstractA new crosslinkable light sensitizer, Ru(2,2′‐bipyridine‐4,4′‐bicarboxylic acid)(4,4′‐bis(11‐dodecenyl)‐2,2′‐bipyridine)(NCS)2, denoted as Ru‐C for titanium oxide nanocrystalline‐based solar cells was synthesized with its crosslinking properties invesitigated by Fourier‐transform infrared and UV‐vis absorption spectroscopies. After crosslinking by itself or copolymerizing with methyacrylic acid, their sensitized solar cells with poly(methylacrylate)‐gelled electrolyte system not only attained more than 5% of power conversion efficiency at AM 1.5 illumination (100 mW/cm2), but also gave rise to long storage life. To the best our knowledge, this is the first crosslinkable dye ever applied to the DSSC in the literature. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 366–372, 2010