N,N-diallyl-N'-acetylhydrazine | 713122-53-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N,N-diallyl-N'-acetylhydrazine
• 英文别名: N',N'-bis(prop-2-enyl)acetohydrazide
• CAS: 713122-53-3
• 化学式: C₈H₁₄N₂O
• 分子量: 154.212
• InChiKey: SFZPPADUHSXGJU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  32.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙酰肼 、 3-溴丙烯 在 sodium 、 异丙醇 作用下， 反应 4.0h， 以36%的产率得到N,N-diallyl-N'-acetylhydrazine
  参考文献：
  名称：

  二烯丙基肼作为多官能水溶性聚合物的单体

  摘要：

  乙酰肼的烯丙基化得到相应的二烯丙基肼，可用于合成水溶性多官能聚合物。

  DOI：

  10.1023/b:rucb.0000019896.10849.fd

文献信息

• Process for preparing pyrazole functionalized benzodiazepinones
  申请人：Harrington Peter J.

  公开号：US20090203901A1

  公开（公告）日：2009-08-13

  The present invention provides innovative strategies for synthesizing pyrazole ring-functionalized benzodiazepinones. Alternative intermediates and high conversion strategies for forming alpha-aminobenzophenone intermediates involve a combination of aromatic acylation, displacement of electronegative leaving groups with amine, and then N-displacement strategies to produce the desired alpha-aminobenzophenone with primary amine functionality. Reaction strategies are then provided for converting alpha-aminobenzophenones to alpha-aminoamidobenzophenone intermediates with high yield and convenient reaction strategies. These alpha-aminoamidobenzophenone intermediates are then converted into benzodiazepinones. These benzodiazepinones are then converted to pyrazole ring functionalized benzodiazepinones through a series of innovative intermediates and/or reaction strategies.

  本发明提供了合成吡唑环功能化苯并二氮杂卓酮的创新策略。形成α-氨基二苯甲酮中间体的替代中间体和高转化策略涉及芳香酰化、用胺置换电负性离去基团以及随后采用N-置换策略以产生具有初级胺功能的所需α-氨基二苯甲酮。随后提供了将α-氨基二苯甲酮转化为高产率且反应条件便利的α-氨基酰胺二苯甲酮中间体的反应策略。这些α-氨基酰胺二苯甲酮中间体随后被转化为苯并二氮杂卓酮。这些苯并二氮杂卓酮通过一系列创新的中间体和/或反应策略转化为吡唑环功能化的苯并二氮杂卓酮。
• Polyalkyldiallylamine-epihalohydrin resins as wet strength additives for papermaking and process for making the same
  申请人：——

  公开号：US20030166791A1

  公开（公告）日：2003-09-04

  The present invention relates to a process for making polyalkyldiallylamine-epihalohydrin resins, the resultant resins and their uses as wet strength additives for papermaking. These resins are obtained by a two step process, wherein the first step comprises the free radical polymerization or copolymerization of an alkyldiallylamine monomer in its protonated form; and the second step comprises reacting an ADAA polymer or copolymer with epihalohydrin under carefully controlled reaction conditions.

  本发明涉及一种制造聚烷基二烯丙基胺-表卤代烃树脂的工艺、所得树脂及其作为造纸湿强度添加剂的用途。这些树脂通过两步法获得，其中第一步包括质子化形式的烷基二烯丙基胺单体的自由基聚合或共聚；第二步包括在严格控制的反应条件下使 ADAA 聚合物或共聚物与表卤醇反应。
• Copolymers Based on Diallylhydrazines
  作者：A. I. Vorob'eva、M. N. Gorbunova、V. Yu. Gusev、R. R. Muslukhov、S. V. Kolesov、A. G. Tolstikov

  DOI：10.1023/b:rjac.0000044167.00715.3b

  日期：2004.7

  The possibility of preparing polymers based on N,N-diallylhydrazine derivatives by allylation of carboxylic acid hydrazides was considered.
• PROCESS FOR MAKING POLYALKYLDIALLYLAMINE-EPIHALOHYDRIN RESINS AS WET STRENGTH ADDITIVES FOR PAPERMAKING
  申请人：HERCULES INCORPORATED

  公开号：EP1461366B1

  公开（公告）日：2012-12-19
• POLYALKYLDIALLYLAMINE-EPIHALOHYDRIN RESINS AS WET STRENGTH ADDITIVES FOR PAPERMAKING AND PROCESS FOR MAKING THE SAME
  申请人：HERCULES INCORPORATED

  公开号：EP1461366A1

  公开（公告）日：2004-09-29