Cr2(tBu2pz)4 | 903899-97-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Cr2(tBu2pz)4
• 英文别名: Cr2(3,5-di-tert-butylpyrazolato)4
• CAS: 903899-97-8
• 化学式: C₄₄H₇₆Cr₂N₈
• 分子量: 821.133
• InChiKey: PITCEBMBFKVPCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4-叔丁基吡啶 、 Cr2(tBu2pz)4 以 正己烷 为溶剂， 以69%的产率得到Cr(tBu2pz)2(tBupy)2
  参考文献：
  名称：

  Synthesis, Structure, and Properties of a Dimeric Chromium(II) Pyrazolato Complex with a Long Chromium−Chromium Distance. Maintenance of a Dimeric Structure in Solution and Interconversion between Dimeric and Monomeric Structures

  摘要：

  The synthesis, solid-state structure, and solution structure of Cr-2(tBu(2)pz)(4) are described. This complex is obtained by sublimation of the monomeric species Cr(tBu(2)pz)(2)(4-tBupy)(2) and contains long chromium-chromium distances that are enforced by the divergent nature of the pyrazolato ligands.

  DOI：

  10.1021/ic060749w
• 作为产物：
  描述：

  4-叔丁基吡啶 以 正己烷 为溶剂， 生成 Cr2(tBu2pz)4
  参考文献：
  名称：

  Synthesis, Structure, and Properties of a Dimeric Chromium(II) Pyrazolato Complex with a Long Chromium−Chromium Distance. Maintenance of a Dimeric Structure in Solution and Interconversion between Dimeric and Monomeric Structures

  摘要：

  The synthesis, solid-state structure, and solution structure of Cr-2(tBu(2)pz)(4) are described. This complex is obtained by sublimation of the monomeric species Cr(tBu(2)pz)(2)(4-tBupy)(2) and contains long chromium-chromium distances that are enforced by the divergent nature of the pyrazolato ligands.

  DOI：

  10.1021/ic060749w