(氨基)二氢硼烷 | 15525-20-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (氨基)二氢硼烷
• 英文名称: (amino)dihydroborane
• 英文别名: cyclodiborazane；1,3-Diazonia-2,4-diboranuidacyclobutane
• CAS: 15525-20-9
• 化学式: B₂H₈N₂
• 分子量: 57.6989
• InChiKey: MXFIHDATIIIFNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.88
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  33.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (氨基)二氢硼烷 生成 ammonia borane
  参考文献：
  名称：

  Boron-Nitrogen Chemistry. I. Syntheses and Properties of New Cycloborazanes, (BH₂NH₂)_n^1,2

  摘要：

  DOI：

  10.1021/ja00971a017
• 作为产物：
  描述：

  c-B5N5(H) 生成 (氨基)二氢硼烷 、 aminodiborane
  参考文献：
  名称：

  Boron-Nitrogen Chemistry. I. Syntheses and Properties of New Cycloborazanes, (BH₂NH₂)_n^1,2

  摘要：

  DOI：

  10.1021/ja00971a017

文献信息

• When is a Nanoparticle a Cluster? An Operando EXAFS Study of Amine Borane Dehydrocoupling by Rh₄_-₆ Clusters
  作者：John L. Fulton、John C. Linehan、Tom Autrey、Mahalingam Balasubramanian、Yongsheng Chen、Nathaniel K. Szymczak

  DOI：10.1021/ja073331l

  日期：2007.10.1

  the structure of the rhodium cluster present during the catalyzed dehydrocoupling of amine boranes under operando conditions. We show how a variety of XAFS strategies can be used in combination with other analytical methods to differentiate homogeneous from heterogeneous systems. Analysis of the in situ XAFS spectra using a series of amine boranes (NH3BH3, R2NHBH3, and RNH2BH3 where R = methyl, isopropyl

  X 射线吸收精细结构 (XAFS) 用于确定在操作条件下胺硼烷催化脱氢偶联过程中存在的铑簇的结构。我们展示了如何将各种 XAFS 策略与其他分析方法结合使用，以区分同类系统和异类系统。使用一系列胺硼烷（NH3BH3、R2NHBH3 和 RNH2BH3，其中 R = 甲基、异丙基、叔丁基和环己基）和铑催化剂前体化合物（包括氯-（1,5-环辛二烯））分析原位 XAFS 光谱铑（I）二聚体，双（1,5-环辛二烯）铑（I）三氟甲磺酸盐，氯二羰基铑（I）二聚体，二氯（五甲基环戊二烯基）铑（III）二聚体，十六羰基六铑，和十二羰基四铑）强烈表明该反应的活性催化剂物质是均相的铑配合物。含有四个或六个铑原子 (Rh(4-6)) 绑定到胺硼烷的铑簇被观察为主要 (> 99%) 含铑物质在催化厌氧脱氢偶联期间和之后。在反应的后期阶段，非金属铑络合物沉淀，其中单个 Rh(4-6) 簇可能形成由具有两个或多个连接位点的反应产物连接的聚合物链。XAFS
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.10, 3.2.4, page 42 - 43
  作者：

  DOI：——

  日期：——
• Zirconium-Catalyzed Amine Borane Dehydrocoupling and Transfer Hydrogenation
  作者：Karla A. Erickson、John P. W. Stelmach、Neil T. Mucha、Rory Waterman

  DOI：10.1021/acs.organomet.5b00415

  日期：2015.10.12

  kappa(5)-(Me3SiNCH2CH2)(2)N-(CH2CH2NSiMe2CH2)Zr (1) has been found to dehydrocouple amine borane substrates, RR'NHBH3 (R = R' = Me; R = Bu-t, R' = H; R = R' = H), at low to moderate catalyst loadings (0.5-5 mol %) and good to excellent conversions, forming mainly borazine and borazane products. Other zirconium catalysts, (N3N)ZrX [(N3N) = N-(CH2CH2NSiMe2CH2)(3), X = NMe2 (2), Cl (3), and (OBu)-Bu-t (4)], were found to exhibit comparable activities to that of 1. Compound 1 reacts with Me2NHBH3 to give (N3N)Zr-(NMe2BH3) (5), which was structurally characterized and features an eta(2) B-H sigma-bond amido borane ligand. Because 5 is unstable with respect to borane loss to form 2, rather than beta-hydrogen elimination, and 2-4 do not exhibit X ligand loss during catalysis, dehydrogenation is hypothesized to proceed via an outer-sphere-type mechanism. This proposal is supported by the catalytic hydrogenation of alkenes by 2 using amine boranes as the sacrificial source of hydrogen.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.4, 4.2.1, page 92 - 95
  作者：

  DOI：——

  日期：——
• Boeddeker, K. W., Dissertation abstracts, Diss. Ohio State Univ., Columbus 1965, S. 1/85, 1965, vol. 26, p. 1904
  作者：Boeddeker, K. W.

  DOI：——

  日期：——