| 1430565-31-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• CAS: 1430565-31-3
• 化学式: C₈₁H₉₄N₄OSZn
• 分子量: 1237.12
• InChiKey: QCEZVZAKZIWNQZ-XFRDCOLYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氰乙酸 在 哌啶 作用下， 以 氯仿 为溶剂， 以72%的产率得到(E)-3-[5-{5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrin-1-yl}thiophen-2-yl]-2-cyanoacrylic acid
  参考文献：
  名称：

  Synthesis and characterization of β-pyrrolic functionalized porphyrins as sensitizers for dye-sensitized solar cells

  摘要：

  New beta-pyrrolic functionalized porphyrins with donor-pi-acceptor character were synthesized and characterized as dye sensitizers for dye-sensitized solar cells. Two types of pi-conjugated spacers, namely benzene and thiophene rings, with cyanoacrylic acid as an acceptor were linked to the porphyrin ring at the beta-pyrrolic position. These porphyrins showed high thermal and electrochemical stability. As sensitizers, the porphyrin dye bearing a thiophene ring as the it-conjugated spacer gave better cell performance with a short-circuit photocurrent density (J(sc)) of 4.57 mA cm(-2), an open-circuit voltage (V-oc) of 0.59 V, and a fill factor (ff) of 0.59, corresponding to an overall conversion efficiency (eta) of 1.94%. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.03.037
• 作为产物：
  描述：

  1-bromo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrin 、 5-醛基-2-噻吩硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 以59%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of β-pyrrolic functionalized porphyrins as sensitizers for dye-sensitized solar cells

  摘要：

  New beta-pyrrolic functionalized porphyrins with donor-pi-acceptor character were synthesized and characterized as dye sensitizers for dye-sensitized solar cells. Two types of pi-conjugated spacers, namely benzene and thiophene rings, with cyanoacrylic acid as an acceptor were linked to the porphyrin ring at the beta-pyrrolic position. These porphyrins showed high thermal and electrochemical stability. As sensitizers, the porphyrin dye bearing a thiophene ring as the it-conjugated spacer gave better cell performance with a short-circuit photocurrent density (J(sc)) of 4.57 mA cm(-2), an open-circuit voltage (V-oc) of 0.59 V, and a fill factor (ff) of 0.59, corresponding to an overall conversion efficiency (eta) of 1.94%. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.03.037