cadmium(II) bis(morpholine dithiocarbamate) | 14024-70-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: cadmium(II) bis(morpholine dithiocarbamate)
• 英文别名: Cd(MDTC)₂；Cd(morpholine-4-dithiocarbamate)₂；(morpholinedithiocarbamate)2 Cd(II)；cadmium(2+);morpholine-4-carbodithioate
• CAS: 14024-70-5
• 化学式: C₁₀H₁₆CdN₂O₂S₄
• 分子量: 436.923
• InChiKey: FEQXBTIUKRAPEC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  19.0
• 可旋转键数：
  0.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  24.94
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  cadmium(II) bis(morpholine dithiocarbamate) 反应 0.03h， 生成 cadmium sulphide
  参考文献：
  名称：

  Precursor dependent morphological and photo-catalytic behaviour of CdS nanostructures

  摘要：

  Cadmium complexes based on Xanthate and dithiocarbamate such as [Cd(ethyl xanthate)2], [Cd(morpholine-4-dithiocarbamate)(2)] and [Cd(piperazine1-dithiocarbamate)(2)] have been used as efficient single source precursors. The formation of CdS nanostructures have been achieved by solvothermal route of synthesis. Crystallographic and morphological characterization of synthesized nanomaterials has been done by X-ray diffraction (XRD) and electron microscopy [Transmission Electron Microscope (TEM)], respectively. Diffraction and electron microscope studies reveal the formation of wurtzite structured CdS nanostructures of various morphologies (nanorods and nanospheres). UV-vis absorption and Fourier transform infrared (FUR) spectroscopic studies have been carried for the detailed optical as well as qualitative analyses. It has been reported that the morphology of synthesized nanomaterials strongly depends upon the type of the precursor complexes. Photo-catalytic activity of the synthesized nano structures has been tested in visible irradiation using methylene blue (MB) dye as a test contaminant in aqueous media. Morphology dependent photo-catalytic activity of the synthesized nanomaterials has been studied in detail to explore the potential of prepared nanostructures to purify polluted water. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2016.10.043
• 作为产物：
  描述：

  吗啉-4-二硫代羧酸钾盐 生成 cadmium(II) bis(morpholine dithiocarbamate)
  参考文献：
  名称：

  Rajesh Kumar Dubey, Puri Bal Krishan, Talanta, 42 (1995) N 1, S 65-72

  摘要：

  DOI：

文献信息

• Synthesis and crystal structure of bis(morpholino dithiocarbamato) Cd(II) complex and its use as precursor for CdS quantum dots using different capping agents
  作者：Lebogang L. R. Mphahlele、Peter A. Ajibade

  DOI：10.1080/17415993.2019.1637876

  日期：2019.11.2

  morpholine dithiocarbamate complex [Cd(morphdtc)2] was synthesized and characterized by single crystal X-ray crystallography. The molecular structure of the complex showed Cd(II) ion in a distorted 4 + 2 octahedral geometry, in which the two morpholine dithiocarbamates act as bidentate chelating and the central Cd ion bond the sulfur atoms of adjacent morpholine acting as bridging ligands to form centrosymmetric

  摘要 合成了镉 (II) 吗啉二硫代氨基甲酸酯复合物 [Cd(morphdtc)2]，并通过单晶 X 射线晶体学表征。配合物的分子结构显示 Cd(II) 离子呈扭曲的 4 + 2 八面体几何形状，其中两个吗啉二硫代氨基甲酸酯作为双齿螯合，中心 Cd 离子键合相邻吗啉的硫原子作为桥接配体形成中心对称五个坐标二聚体分子。使用三种不同的封端剂在 180°C 下热解 Cd(II) 复合物以制备 CdS 纳米颗粒。pXRD 图案揭示了 CdS 纳米晶体的六方晶相和立方晶相的混合物。TEM 图像显示半球形和球形纳米粒子，OLM-CdS 的尺寸范围为 4.50-5.70 nm，HDA-CdS 的尺寸范围为 3.33-5.96 nm，ODA-CdS 的尺寸范围为 3.00-5.83 nm。CdS 纳米晶的粒径分布在 1.06 nm (SD ± 0.73) 范围内，OLM-CdS 为 0.68 nm，HDA-CdS