Pd(CH3)(N-(2,6-diisopropylphenyl)-3-hydroxysalicylaldiminato)(triphenylphosphine) | 1279647-60-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Pd(CH3)(N-(2,6-diisopropylphenyl)-3-hydroxysalicylaldiminato)(triphenylphosphine)
• CAS: 1279647-60-7
• 化学式: C₃₈H₄₀NO₂PPd
• 分子量: 680.135
• InChiKey: OIGAVFHCMSOFID-IOZRKMGDSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Pd(CH3)(N-(2,6-diisopropylphenyl)-3-hydroxysalicylaldiminato)(triphenylphosphine) 、 potassium tert-butylate 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Palladium(II) complexes bearing a salicylaldiminato ligand with a hydroxyl group: Synthesis, structures, deprotonation, and catalysis

  摘要：

  Palladium complexes with a salicylaldiminato ligand bearing a hydroxyl group (1a and 1b) have been synthesized and characterized. The structures of these complexes were confirmed by X-ray crystallography. A reversible deprotonation/protonation of the hydroxyl moiety on 1b was observed, while such behaviour was impossible with a related palladium complex (1c) bearing a methoxyl group in place of the hydroxyl group. The deprotonation affected its catalytic behaviour: the activity for polymerization of methyl acrylate catalyzed by 1b considerably decreased in the presence of 1 equiv. of (BuOK)-Bu-t. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.036
• 作为产物：
  描述：

  盐酸 、 以 四氢呋喃 、 乙醚 为溶剂， 生成 Pd(CH3)(N-(2,6-diisopropylphenyl)-3-hydroxysalicylaldiminato)(triphenylphosphine)
  参考文献：
  名称：

  Palladium(II) complexes bearing a salicylaldiminato ligand with a hydroxyl group: Synthesis, structures, deprotonation, and catalysis

  摘要：

  Palladium complexes with a salicylaldiminato ligand bearing a hydroxyl group (1a and 1b) have been synthesized and characterized. The structures of these complexes were confirmed by X-ray crystallography. A reversible deprotonation/protonation of the hydroxyl moiety on 1b was observed, while such behaviour was impossible with a related palladium complex (1c) bearing a methoxyl group in place of the hydroxyl group. The deprotonation affected its catalytic behaviour: the activity for polymerization of methyl acrylate catalyzed by 1b considerably decreased in the presence of 1 equiv. of (BuOK)-Bu-t. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.036