SnBu2(PhCONNCPh)2 | 1251563-90-2

• 分子结构分类: 有机化合物
• 英文名称: SnBu2(PhCONNCPh)2
• CAS: 1251563-90-2
• 化学式: C₃₆H₃₈N₄O₂Sn
• 分子量: 677.433
• InChiKey: TWIOUGRSNQKMBZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Benzil-bis-benzoylhydrazon 、 二丁基二氯化锡 在 Et₃N 作用下， 以 二氯甲烷 为溶剂， 以87%的产率得到SnBu2(PhCONNCPh)2
  参考文献：
  名称：

  Luminescent organotin complexes with the ligand benzil bis(benzoylhydrazone)

  摘要：

  Three organotin complexes have been synthesised by reaction of the ligand benzil bis(benzoylhydrazone) LH2 with SnR2Cl2 or SnR3Cl (R = Me, Bu, Ph). In all the compounds the ligand is doubly deprotonated and behaves as N2O2 tetradentate chelate, leading to distorted octahedral arrangements with the ligand in the equatorial plane and the organic groups in the axial positions. The complexes have been fully characterised by spectroscopic techniques including C-13 and Sn-119 NMR in solution and in the solid state, which confirm that the structure found in the solid state is retained in chloroform solution, and two of them by single crystal X-ray diffraction. The luminescent properties of the ligand and its complexes have also been tested as well as the effect of pH, the addition of acetone and the ionic strength over the luminescence intensity. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.07.002