[(2R,3R,4R,6S)-6-[(2S,3S,6S)-6-[(2R,3R,4R,6S)-6-[(2R,3R,4R,6S)-3-benzoyloxy-2-methyl-6-[4-(2-trimethylsilylethoxymethoxy)phenoxy]oxan-4-yl]oxy-2-methyl-4-(naphthalen-2-ylmethoxy)oxan-3-yl]oxy-2-methyloxan-3-yl]oxy-2-methyl-4-[(2S,4R,5R,6R)-6-methyl-4-[(2S,5S,6S)-6-methyl-5-(4-oxopentanoyloxy)oxan-2-yl]oxy-5-[2-(4-nitrophenyl)ethylsulfonyloxy]oxan-2-yl]oxyoxan-3-yl] benzoate | 1237527-29-5

分子结构分类

有机化合物 - 苯类化合物 - 蒽

中文名称

——

中文别名

——

英文名称

[(2R,3R,4R,6S)-6-[(2S,3S,6S)-6-[(2R,3R,4R,6S)-6-[(2R,3R,4R,6S)-3-benzoyloxy-2-methyl-6-[4-(2-trimethylsilylethoxymethoxy)phenoxy]oxan-4-yl]oxy-2-methyl-4-(naphthalen-2-ylmethoxy)oxan-3-yl]oxy-2-methyloxan-3-yl]oxy-2-methyl-4-[(2S,4R,5R,6R)-6-methyl-4-[(2S,5S,6S)-6-methyl-5-(4-oxopentanoyloxy)oxan-2-yl]oxy-5-[2-(4-nitrophenyl)ethylsulfonyloxy]oxan-2-yl]oxyoxan-3-yl] benzoate

英文别名

——

[(2R,3R,4R,6S)-6-[(2S,3S,6S)-6-[(2R,3R,4R,6S)-6-[(2R,3R,4R,6S)-3-benzoyloxy-2-methyl-6-[4-(2-trimethylsilylethoxymethoxy)phenoxy]oxan-4-yl]oxy-2-methyl-4-(naphthalen-2-ylmethoxy)oxan-3-yl]oxy-2-methyloxan-3-yl]oxy-2-methyl-4-[(2S,4R,5R,6R)-6-methyl-4-[(2S,5S,6S)-6-methyl-5-(4-oxopentanoyloxy)oxan-2-yl]oxy-5-[2-(4-nitrophenyl)ethylsulfonyloxy]oxan-2-yl]oxyoxan-3-yl] benzoate化学式

CAS

1237527-29-5

化学式

C₈₆H₁₀₉NO₂₇SSi

mdl

——

分子量

1648.95

InChiKey

ZBHMGIRUSZGRJJ-PXPVJATFSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

13.61
重原子数：

116
可旋转键数：

37
环数：

12.0
sp3杂化的碳原子比例：

0.56
拓扑面积：

332
氢给体数：

0
氢受体数：

27

反应信息

作为反应物：

描述：

[(2R,3R,4R,6S)-6-[(2S,3S,6S)-6-[(2R,3R,4R,6S)-6-[(2R,3R,4R,6S)-3-benzoyloxy-2-methyl-6-[4-(2-trimethylsilylethoxymethoxy)phenoxy]oxan-4-yl]oxy-2-methyl-4-(naphthalen-2-ylmethoxy)oxan-3-yl]oxy-2-methyloxan-3-yl]oxy-2-methyl-4-[(2S,4R,5R,6R)-6-methyl-4-[(2S,5S,6S)-6-methyl-5-(4-oxopentanoyloxy)oxan-2-yl]oxy-5-[2-(4-nitrophenyl)ethylsulfonyloxy]oxan-2-yl]oxyoxan-3-yl] benzoate 在 sodium methylate 作用下，以四氢呋喃、甲醇为溶剂，生成

参考文献：

名称：

10.1002/asia.200900640.

摘要：

DOI：

10.1002/asia.200900640.
作为产物：

描述：

[(2R,3R,4R,6S)-4-[(2S,4R,5R,6R)-5-[(2S,5S,6S)-5-hydroxy-6-methyloxan-2-yl]oxy-6-methyl-4-(naphthalen-2-ylmethoxy)oxan-2-yl]oxy-2-methyl-6-[4-(2-trimethylsilylethoxymethoxy)phenoxy]oxan-3-yl] benzoate 、 [(2R,3R,4R)-2-methyl-4-[(2S,4R,5R,6R)-6-methyl-4-[(2S,5S,6S)-6-methyl-5-(4-oxopentanoyloxy)oxan-2-yl]oxy-5-[2-(4-nitrophenyl)ethylsulfonyloxy]oxan-2-yl]oxy-6-(2,2,2-trichloroethanimidoyl)oxyoxan-3-yl] benzoate 在三乙基硅烷、碘作用下，以甲苯为溶剂，反应 3.5h，生成 [(2R,3R,4R,6S)-6-[(2S,3S,6S)-6-[(2R,3R,4R,6S)-6-[(2R,3R,4R,6S)-3-benzoyloxy-2-methyl-6-[4-(2-trimethylsilylethoxymethoxy)phenoxy]oxan-4-yl]oxy-2-methyl-4-(naphthalen-2-ylmethoxy)oxan-3-yl]oxy-2-methyloxan-3-yl]oxy-2-methyl-4-[(2S,4R,5R,6R)-6-methyl-4-[(2S,5S,6S)-6-methyl-5-(4-oxopentanoyloxy)oxan-2-yl]oxy-5-[2-(4-nitrophenyl)ethylsulfonyloxy]oxan-2-yl]oxyoxan-3-yl] benzoate 、 [(2R,3R,4R,6R)-6-[(2S,3S,6S)-6-[(2R,3R,4R,6S)-6-[(2R,3R,4R,6S)-3-benzoyloxy-2-methyl-6-[4-(2-trimethylsilylethoxymethoxy)phenoxy]oxan-4-yl]oxy-2-methyl-4-(naphthalen-2-ylmethoxy)oxan-3-yl]oxy-2-methyloxan-3-yl]oxy-2-methyl-4-[(2S,4R,5R,6R)-6-methyl-4-[(2S,5S,6S)-6-methyl-5-(4-oxopentanoyloxy)oxan-2-yl]oxy-5-[2-(4-nitrophenyl)ethylsulfonyloxy]oxan-2-yl]oxyoxan-3-yl] benzoate

参考文献：

名称：

10.1002/asia.200900640.

摘要：

DOI：

10.1002/asia.200900640.

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