bis-(2-nitrophenyl)furoxan | 132371-23-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: bis-(2-nitrophenyl)furoxan
• 英文别名: Bis(2-nitrophenyl)furoxan；3,4-bis(2-nitrophenyl)-2-oxido-1,2,5-oxadiazol-2-ium
• CAS: 132371-23-4
• 化学式: C₁₄H₈N₄O₆
• 分子量: 328.241
• InChiKey: CNMGMDSWNSLQGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  143
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  o-nitrobenzonitrile N-oxide 、 氧化亚氮 生成 bis-(2-nitrophenyl)furoxan
  参考文献：
  名称：

  RAKITIN, O. A.;OGURTSOV, V. A.;GODOVIKOVA, T. I.;XMELNITSKIJ, L. I., IZV. AN CCCP. CEP. XIM.,(1990) N, S. 1623-1625

  摘要：

  DOI：

文献信息

• Syntheses based on nitrile oxides. 1. Reaction of aromatic nitrile oxides with N-cyanimides
  作者：V. A. Ogurtsov、O. A. Rakitin、N. V. Obruchnikova、L. F. Chertanova、A. A. Gazikasheva、L. I. Khmel'nitskii

  DOI：10.1007/bf00958257

  日期：1990.9

  The reaction of trialkylaminocyanimides with aromatic nitrile oxides leads to trialkylamino-(3-aryl-1,2,4-oxadiazol-5-yl)imides, while the corresponding reactions with sulfylcyanimines and phosphincyanimides do not take place. Using x-ray structural analysis the principal structural features of the 1,2,4-oxadiazole products have been elucidated.
• Reactions of nitrile oxides with nitrogen oxides. 2. Reactions with nitrogen monoxide and nitrogen sesquioxide
  作者：O. A. Rakitin、V. A. Ogurtsov、T. I. Godovikova、L. I. Khmel'nitskii

  DOI：10.1007/bf00957863

  日期：1990.7

  We have studied the reactions of aromatic nitrile oxides with nitrogen monoxide and nitrogen sesquioxide. It was shown that nitrogen monoxide removes an oxygen atom from the nitrile oxide with formation of the corresponding nitrile and nitrogen dioxide. The reaction products with nitrogen sesquioxide are formed as a result of reactions of the nitrile oxide with nitrogen monoxide and nitrogen tetroxide.