(pentachlorophenyl)(tetrachloro-4-formylphenyl)(tetrachloro-2-pyridyl)methane | 135782-04-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (pentachlorophenyl)(tetrachloro-4-formylphenyl)(tetrachloro-2-pyridyl)methane
• 英文别名: 2,3,5,6-tetrachloro-4-[(2,3,4,5,6-pentachlorophenyl)-(3,4,5,6-tetrachloropyridin-2-yl)methyl]benzaldehyde
• CAS: 135782-04-6
• 化学式: C₁₉H₂Cl₁₃NO
• 分子量: 721.12
• InChiKey: OZIWKVBGLHAFNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.57
• 重原子数：
  34.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  29.96
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (pentachlorophenyl)(tetrachloro-4-formylphenyl)(tetrachloro-2-pyridyl)methane 在 sodium hydroxide 、 potassium permanganate 、 碘 、 二甲基亚砜 作用下， 以 丙酮 为溶剂， 反应 26.75h， 生成 (4-carboxytetrachlorophenyl)(pentachlorophenyl)(tetrachloro-2-pyridyl)methyl radical
  参考文献：
  名称：

  Monofunctionalized tridecachlorodiphenyl (2-pyridyl)methyl radicals. Synthesis and spectral analysis

  摘要：

  Highly chlorinated diphenyl(2-pyridyl)methyl radicals and their alpha-H precursors with a carboxy, chlorocarbonyl, or allyloxycarbonyl substituent in the 4-position of one phenyl ring have been synthesized. All of them are stable red solids, completely dissociated (magnetic susceptibility), decomposing when melting (200-240-degrees-C). Their ESR, UV-VIS and IR spectra are given.

  DOI：

  10.1039/p19910001101
• 作为产物：
  描述：

  (pentachlorophenyl)<2,3,5,6-tetrachloro-4-(dichloromethyl)phenyl>(tetrachloro-2-pyridyl)methane 在 硫酸 、 水 作用下， 反应 24.0h， 以96%的产率得到(pentachlorophenyl)(tetrachloro-4-formylphenyl)(tetrachloro-2-pyridyl)methane
  参考文献：
  名称：

  Monofunctionalized tridecachlorodiphenyl (2-pyridyl)methyl radicals. Synthesis and spectral analysis

  摘要：

  Highly chlorinated diphenyl(2-pyridyl)methyl radicals and their alpha-H precursors with a carboxy, chlorocarbonyl, or allyloxycarbonyl substituent in the 4-position of one phenyl ring have been synthesized. All of them are stable red solids, completely dissociated (magnetic susceptibility), decomposing when melting (200-240-degrees-C). Their ESR, UV-VIS and IR spectra are given.

  DOI：

  10.1039/p19910001101

文献信息

• JULIA, LUIS;RIERA, JUAN;TEIXIDO, RAMON, J. CHEM. SOC. PERKIN TRANS. I ,(1991) N, C. 1101-1105
  作者：JULIA, LUIS、RIERA, JUAN、TEIXIDO, RAMON

  DOI：——

  日期：——