2(3),9(10),16(17),23(24)-tetra(4-pyridinemethoxy)phthalocyanine | 1051382-61-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2(3),9(10),16(17),23(24)-tetra(4-pyridinemethoxy)phthalocyanine
• CAS: 1051382-61-6
• 化学式: C₅₆H₃₈N₁₂O₄
• 分子量: 942.996
• InChiKey: YFUCEEQYCFJKTQ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2(3),9(10),16(17),23(24)-tetra(4-pyridinemethoxy)phthalocyanine 、 2-氯乙醇 反应 5.0h， 以51%的产率得到2(3),9(10),16(17),23(24)-tetra[4-(N-2-oxyethyl)pyridinemethoxy]phthalocyanine chloride
  参考文献：
  名称：

  Synthesis and spectral characteristics of water-soluble pyridine-containing phthalocyanines of cation type

  摘要：

  Soluble in aqueous acids phthalocyanine ligands and metallophthalocyanines, containing the peripheral pyridine fragments were synthesized from the corresponding phthalodinitriles. The quaternization of the pyridine-containing phthalocyanines using 2-chloroethanol afforded water-soluble phthalocyanine ligands and metal complexes. The new compounds were characterized by NMR, EAS, and MALDI-TOF mass spectrometry.

  DOI：

  10.1134/s1070363213100198
• 作为产物：
  描述：

  lithium 2(3),9(10),16(17),23(24)-tetra(4-pyridinemethoxy)phthalocyaninate 在 溶剂黄146 作用下， 以 丙酮 为溶剂， 反应 1.0h， 以69%的产率得到2(3),9(10),16(17),23(24)-tetra(4-pyridinemethoxy)phthalocyanine
  参考文献：
  名称：

  Synthesis and spectral characteristics of water-soluble pyridine-containing phthalocyanines of cation type

  摘要：

  Soluble in aqueous acids phthalocyanine ligands and metallophthalocyanines, containing the peripheral pyridine fragments were synthesized from the corresponding phthalodinitriles. The quaternization of the pyridine-containing phthalocyanines using 2-chloroethanol afforded water-soluble phthalocyanine ligands and metal complexes. The new compounds were characterized by NMR, EAS, and MALDI-TOF mass spectrometry.

  DOI：

  10.1134/s1070363213100198