| 184352-63-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 184352-63-4
• 化学式: C₇H₇O₃S*C₄₅H₄₁O₆P₂PdS
• 分子量: 1049.45
• InChiKey: FNBIAPDZEAZIIW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  PdCl2((S)-MeO-biphep) 、 水 、 silver(I) 4-methylbenzenesulfonate 以 四氢呋喃 为溶剂， 以87%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Cationic Palladium (6,6‘-Dimethoxybiphenyl-2,2‘-diyl)bis(diphenylphosphine) Complexes

  摘要：

  For compounds of the type [(MeO-BIPHEP)P6X(2)] (where MeO-BIPHEP is (6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) and X is an anion with low coordination ability) one or both anions X, depending on their nature, are displaced in an outer coordination sphere due to water coordination. The compounds are easily reduced in methanolic solution. With the diaquo complex [{(S)-MeO-BIPHEP}Pd(H2O)(2)](OTf)(2) as starting material, the formation of the dimeric palladium(I) complex [{(S)-MeO-BIPHEP}Pd](2)(OTf)(2) is observed. In contrast, under CO pressure, the mu-hydrido mu-carbonyl binuclear palladium(I) complex [{(s)-MeO-BIPHEP}Pd(mu-H)(mu-CO)Pd{(S)-MeO-BIPHEP}]OTf is formed. The molecular structures of [{(S)-MeO-BIPHEP}Pd(H2O)(THF)](OTf)(2) and [{(S)-MeO-BIPHEP}Pd(OTfa)(2)] were determined by X-ray diffraction.

  DOI：

  10.1021/om960445p