tetrakis(glycyloxy)di(hydrazin-1-ium-2-yl)zincate(IV) | 175663-49-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tetrakis(glycyloxy)di(hydrazin-1-ium-2-yl)zincate(IV)
• CAS: 175663-49-7
• 化学式: C₈H₂₆N₈O₈Zn
• 分子量: 427.733
• InChiKey: KMZHNYHLTRYABO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tetrakis(glycyloxy)di(hydrazin-1-ium-2-yl)zincate(IV) 以 neat (no solvent) 为溶剂， 生成 锌
  参考文献：
  名称：

  Thermal, spectral and magnetic studies on glycine complexes of cobalt(II), nickel(II) and zinc(II) with hydrazine

  摘要：

  Hydrazinium metal glycinates [(N2H5)(2)M(NH2CH2COO)(4)] and bis(hydrazine)metal glycinates, [M(NH2CH2COO)(2)(N2H4)(2)], where M = Co, Ni or Zn have been prepared and characterized by chemical analyses, magnetic moments and vibrational and electronic spectra. The thermal behaviour of these compounds has been studied by thermogravimetry and differential thermal analyses. These complexes decompose with high exothermicity giving metal powder as the final residue. The X-ray powder data of each set of complexes show isomorphism among themselves.

  DOI：

  10.1007/bf01979952
• 作为产物：
  描述：

  聚甘氨酸 、 zinc(II) nitrate hexahydrate 、 hydrazine hydrate 以 水 为溶剂， 以80%的产率得到tetrakis(glycyloxy)di(hydrazin-1-ium-2-yl)zincate(IV)
  参考文献：
  名称：

  Thermal, spectral and magnetic studies on glycine complexes of cobalt(II), nickel(II) and zinc(II) with hydrazine

  摘要：

  Hydrazinium metal glycinates [(N2H5)(2)M(NH2CH2COO)(4)] and bis(hydrazine)metal glycinates, [M(NH2CH2COO)(2)(N2H4)(2)], where M = Co, Ni or Zn have been prepared and characterized by chemical analyses, magnetic moments and vibrational and electronic spectra. The thermal behaviour of these compounds has been studied by thermogravimetry and differential thermal analyses. These complexes decompose with high exothermicity giving metal powder as the final residue. The X-ray powder data of each set of complexes show isomorphism among themselves.

  DOI：

  10.1007/bf01979952