Ph3P=NC(O)But | 1053362-85-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ph3P=NC(O)But
• 英文别名: 2,2-dimethyl-N-(triphenyl-lambda5-phosphanylidene)propanamide；2,2-dimethyl-N-(triphenyl-λ5-phosphanylidene)propanamide
• CAS: 1053362-85-8
• 化学式: C₂₃H₂₄NOP
• 分子量: 361.423
• InChiKey: AJCPOMQAWRKOIT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  29.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三甲基乙酸酐 、 三苯基膦 在 sodium azide 作用下， 以 丙酮 为溶剂， 反应 72.17h， 以62%的产率得到Ph3P=NC(O)But
  参考文献：
  名称：

  Synthesis and characterisation of isomeric cycloaurated complexes derived from the iminophosphorane Ph3PNC(O)Ph

  摘要：

  Using different organomercury substrates, two isomeric cycloaurated complexes derived from the stabilised iminophosphorane Ph3P=NC(O)Ph were prepared. Reaction of Ph3P=NC(O)Ph with PhCH2Mn(CO)(5) gave the manganated precursor (CO)(4)Mn(2-C6H4C(O)N=PPh3), metallated on the C(O)Ph substituent, which yielded the organomercury complex ClHg(2-C6H4C(O)N=PPh3) by reaction with HgCl2 in methanol. Transmetallation of the mercurated derivative with Me4N[AuCl4] gave the cycloaurated iminophosphorane AuCl2(2-C6H4C(O)N=PPh3) with an exo PPh3 substituent. The endo isomer AuCl2(2-C6H4Ph2P=NC(O)Ph) [aurated on a PPh3 ring] was obtained by an independent reaction sequence, involving reaction of the diarylmercury precursor Hg(2-C6H4P(=NC(O)Ph)Ph-2)(2) [prepared from the known compound Hg(2-C6H4PPh2)(2) and PhC(O)N-3] with Me4N[AuCl4]. Both of the isomeric iminophosphorane derivatives were structurally characterised, together with the precursors (2-HgClC6H4)C(O)N=PPh3 and (CO)(4)Mn(2-C6H4C(O)N=PPh3). The utility of P-31 NMR spectroscopy in monitoring reaction chemistry in this system is described. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.019

文献信息

• Generation of Nitrene by the Photolysis of <i>N</i>-Substituted Iminodibenzothiophene
  作者：Hiroyuki Morita、Atsushi Tatami、Tetsuo Maeda、Byung Ju Kim、Wataru Kawashima、Toshiaki Yoshimura、Hitoshi Abe、Takeshi Akasaka

  DOI：10.1021/jo800604t

  日期：2008.9.19

  To evaluate the ability of dibenzothiophene N-substituted sulfilimines as photochemical nitrene sources, their photolyses in the presence of several trapping reagents, such as sulfides, olefins, and phosphorus compounds, were performed. In the reactions, the corresponding imino-transfer compounds, namely sulfilimines, aziridines, and iminophosphoranes, were formed in good yields, indicating dibenzothiophene N-tosyl and N-acylsulfilimines have a potent nature as nitrogen sources.