bis[1-(4-fluorophenyl)-1,3-butanedione]-palladium(II) | 98292-88-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis[1-(4-fluorophenyl)-1,3-butanedione]-palladium(II)
• CAS: 98292-88-7
• 化学式: C₂₀H₁₆F₂O₄Pd
• 分子量: 464.761
• InChiKey: QZHWVQVFMRTFIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-(4-氟苯基)-1,3-丁二酮 、 sodium hexachlorodipalladate(II) 在 sodium carbonate 作用下， 以 甲醇 为溶剂， 生成 bis[1-(4-fluorophenyl)-1,3-butanedione]-palladium(II)
  参考文献：
  名称：

  Joshi, Krishna C.; Joshi, Bidya S., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1985, vol. 24, # 6, p. 527 - 528

  摘要：

  DOI：

文献信息

• Synthesis and Spectral Studies of Some New bis(1,3‐Diketonato)palladium(II) Complexes
  作者：Vijai N. Pathak、Chandra K. Oza、Ragini Gupta、Ranjana Tiwari、Sarita Chaudhary

  DOI：10.1081/sim-120020327

  日期：2003.1.6

  Bis(1,3-diketonato)palladium(II) complexes were synthesized by three routes. In route one, sodium hexachlorodipalladate in methanol was treated with the appropriately substituted diaryl-1,3-diketones using sodium carbonate, while in route two substituted diaryl-1,3-diketones were treated with palladium chloride in acetone to afford the desired bis(1,3-diketonato)palladium(II). In route three 1,3-bis(substituted aryl)prop-2-enones were treated with palladium chloride and sodium hydrogen carbonate in THF to provide the oxygen insertion product, bis(1,3-diketonato)palladium(II) complexes. All synthesized compounds were characterized on the basis of spectral and analytical data.