N-Phenylsulfanyl-formamide | 36254-08-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Phenylsulfanyl-formamide
• 英文别名: N-phenylsulfanylformamide
• CAS: 36254-08-7
• 化学式: C₇H₇NOS
• 分子量: 153.205
• InChiKey: DNSWTMBKSOFRIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯硫酚 、 formamide 在 copper(l) iodide 、 1,5,7-三氮杂双环[4.4.0]癸-5-烯 、 氧气 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以12%的产率得到N-Phenylsulfanyl-formamide
  参考文献：
  名称：

  铜催化合成N-甲酰基/酰基次磺酰胺和-硫代磺酰胺

  摘要：

  最近铜催化氧化键形成的显着成功使我们开发了一种环境友好的铜催化硫氮键形成反应，以提供合成和工业上有用的缺电子次磺酰胺。通过引入 1,5,7-三氮杂双环 [4.4.0]dec-5-烯添加剂，克服了 N-甲酰基/酰基-和磺酰胺的低亲核性。以良好的产率合成了多种 N-甲酰基/酰基亚磺酰胺和 -硫代磺酰胺，而硫不会过度氧化。相关的机理研究支持了所提出的反应机理。

  DOI：

  10.1002/ejoc.201500857

文献信息

• Copolymers of amino acids and methods of their production
  申请人：——

  公开号：US20040006198A1

  公开（公告）日：2004-01-08

  Disclosed are copolymers based on aspartic acid or its precursor molecules and methods of their production. The copolymers are water-soluble over a wide range of composition and molecular weight. Their preparation involves conversion of a polysuccinimide to copolymers of defined composition, containing aspartate and succinimide residues and/or residues of asparagine. In particular, the copolymers include water-soluble terpolymers of asp artate, asp aragine, and succinimide.

  本发明涉及基于天冬氨酸或其前体分子的共聚物及其生产方法。这些共聚物在组成和分子量的广泛范围内都是水溶性的。它们的制备涉及将多聚琥珀酰亚胺转化为具有定义组成的共聚物，其中包含天冬氨酸和琥珀酰亚胺残基和/或天冬氨酰残基。特别是，这些共聚物包括天冬氨酸、天冬氨酰和琥珀酰亚胺的水溶性三元共聚物。
• Amino acid and carbohydrate polymers for use in soil retention, water conservation, water clarification, and dust control
  申请人：Sikes Steven C.

  公开号：US20070085055A1

  公开（公告）日：2007-04-19

  Water-soluble amino acid copolymers, modified polysaccharides, acrylamide polymers, and combinations thereof, are described, for uses including flocculation of solids, particularly flocculation of soil, such as in an agricultural setting. Also described are methods of preparing selected amino acid copolymers and modified polysaccharides.

  本文介绍了水溶性氨基酸共聚物、改性多糖、丙烯酰胺聚合物及其组合物的用途，包括固体絮凝，特别是土壤絮凝，例如在农业环境中。还描述了制备选定氨基酸共聚物和改性多糖的方法。
• AMINO ACID, CARBOHYDRATE AND ACRYLAMIDE POLYMERS USEFUL AS FLOCCULANTS IN AGRICULTURAL AND INDUSTRIAL SETTINGS
  申请人：Sikes C. Steven

  公开号：US20090127205A1

  公开（公告）日：2009-05-21

  Modified polysaccharides, acrylamide copolymers, water-soluble amino acid copolymers, and combinations thereof are described for uses including flocculation of solids, particularly flocculation of soil in an agricultural settings and clarification of process waters from oil-sands mining operations. Also described are methods of preparing selected amino acid copolymers and modified polysaccharides.

  本文描述了改性多糖、丙烯酰胺共聚物、水溶性氨基酸共聚物及其组合物的用途，包括固体絮凝，特别是在农业环境中的土壤絮凝和油砂采矿过程水的澄清。还描述了制备选定氨基酸共聚物和改性多糖的方法。
• Copolymers of amino acids, methods of their production, and uses thereof
  申请人：Sikes C. Steven

  公开号：US20060287499A1

  公开（公告）日：2006-12-21

  Disclosed are copolymers based on aspartic acid or its precursor molecules and methods of their production. The copolymers are water-soluble over a wide range of composition and molecular weight. Their preparation involves conversion of a polysuccinimide to copolymers of defined composition, containing aspartate and succinimide residues and/or residues of asparagine. In particular, the copolymers include water-soluble terpolymers of aspartate, asparagine, and succinimide.

  本发明涉及基于天冬氨酸或其前体分子的共聚物及其制备方法。这些共聚物在组成和分子量范围内都是水溶性的。它们的制备涉及将聚琥珀酰亚胺转化为具有定义组成的共聚物，其中包含天冬氨酸和琥珀酰亚胺残基和/或天冬氨酰胺残基。特别地，这些共聚物包括天冬氨酸、天冬氨酰胺和琥珀酰亚胺的水溶性三元共聚物。
• A method for detecting amino acid derivatives
  申请人：SEIKO INSTRUMENTS INC.

  公开号：EP0353361A1

  公开（公告）日：1990-02-07

  A method for detecting an amino acid derivative comprises the steps of: reacting a 2-anilino-5-­thiazolinone derivative of the general formula (a) below with an amino compound of fluorescein or an amino compound of rhodamine derivatives of the general formula (b) below to form a phenylthiocarbamyl amino acid derivative of the general formula (c) below; and detecting said phenylthio-carbamyl amino acid derivative wherein X is a fluorescein or a rhodamine derivative and R1 is an amino acid side chain.

  一种检测氨基酸衍生物的方法，包括以下步骤： 将以下通式(a)的 2-苯胺基-5-噻唑啉酮衍生物与以下通式(b)的荧光素的氨基化合物或罗丹明衍生物的氨基化合物反应，形成以下通式(c)的苯硫基氨基甲酸酯衍生物；检测所述苯硫基氨基甲酸酯衍生物。 其中 X 为荧光素或罗丹明衍生物，R1 为氨基酸侧链。