| 333752-70-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 333752-70-8
• 化学式: C₁₃H₁₉N₅NiO
• 分子量: 320.017
• InChiKey: FRPMRCSIDWODLX-IVKCLRODSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) acetate tetrahydrate 、 水杨醛-二乙基氨基乙基胺盐 、 sodium azide 以 甲醇 、 水 为溶剂， 生成 nickel(II) tetra-tert-butylphthalocyanine 、
  参考文献：
  名称：

  Synthesis, characterization and crystal structures of some four coordinated nickel(II) complexes with tridentate Schiff base ligands

  摘要：

  A number of Ni(II) complexes with tridentate Schiff base ligands with a N2O donor set and coordinating NNN- and SCN- anions have been synthesized and characterized by analytical, spectroscopic and electrochemical techniques. X-ray structure analyses of three of these complexes [(LNi)-Ni-1(NNN)] (1), [(LNi)-Ni-2(NNN)] (2) and [(LNi)-Ni-3(NCS)] (6) [HL1 = Me2NCH2CH2N(Me)C6H4OH, HL2 = Et2NCH2CH2N(H)C6H4OH, HL3 = Et2NCH2CH2N(H)C6H3BrOH] show that the nickel atom has a square planar geometry. Thermogravimetric studies show multiple step decomposition, and electrochemical studies indicate that the complexes are irreversibly oxidized to Ni(III) species, which are unstable and undergo rapid decomposition. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00601-x