4-(Thiocyanato)butyl 2-methylprop-2-enoate | 76392-31-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-(Thiocyanato)butyl 2-methylprop-2-enoate
• 英文别名: 4-thiocyanatobutyl 2-methylprop-2-enoate
• CAS: 76392-31-9
• 化学式: C₉H₁₃NO₂S
• 分子量: 199.274
• InChiKey: WXQPSNQRLRLQKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  75.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  Methacrylsaeure-(4-chlor-n-butyl)ester 、 potassium thioacyanate 在 甲基三苯基溴化膦 、 potassium iodide 作用下， 以 丁酮 为溶剂， 反应 55.0h， 以81%的产率得到4-(Thiocyanato)butyl 2-methylprop-2-enoate
  参考文献：
  名称：

  硫氰酸根合烷基（甲基）丙烯酸酯的新合成

  摘要：

  摘要 在相转移催化下，由相应的氯代和溴代烷基（甲基）丙烯酸酯与硫氰酸钾在碘化钾存在下选择性合成硫氰酸根合烷基甲基（丙烯酸）酯，产率为 71% 至 95%。

  DOI：

  10.1080/00397919208019260

文献信息

• Process for synthesis of polymer compositions, polymer compositions obtainable by the process, and use of the same
  申请人：RohMax Additives GmbH

  公开号：US20030060587A1

  公开（公告）日：2003-03-27

  The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt%, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.

  本发明涉及一种合成聚合物组合物的过程，其具有降低催化剂含量的效果。在该过程中，含有少于0.5重量％的至少含有一个羧基，磺酸基和/或至少一个膦酸基的乙烯基不饱和单体相对于乙烯基不饱和单体的总重量进行聚合，通过含有可转移原子团的引发剂和至少一种过渡金属的催化剂，在与可以形成与金属催化剂或催化剂配合物的配体一起的情况下进行聚合，在聚合之后，聚合物中的催化剂至少部分被分离。为此，在聚合之后，通过至少一种过滤助剂过滤聚合物组合物，该过滤助剂相对于总重量含有至少0.5重量％的重复单元，其中包含至少一个羧酸基，磺酸基和/或至少一个膦酸基。
• Graft copolymers based on polyolefin backbone and methacrylate side chains
  申请人：Evonik Oil Additives GmbH

  公开号：US10385288B1

  公开（公告）日：2019-08-20

  A graft copolymer can include, in its backbone, at least one segment having repeating units obtainable by ring-opening metathesis polymerization (ROMP) of an optionally substituted cycloalkene, and at least one segment comprising repeating units obtainable by atom transfer radical polymerization (ATRP) of a (meth)acrylate. The corresponding graft copolymer is highly suitable for use as an oil additive in internal combustion engines, in particular, in combustion engines which are operated for longer periods of time at substantially constant operating temperatures.

  接枝共聚物的骨架可包括至少一个具有可通过任选取代的环烷烃的开环偏聚（ROMP）而获得的重复单元的段，以及至少一个包含可通过（甲基）丙烯酸酯的原子转移自由基聚合（ATRP）而获得的重复单元的段。相应的接枝共聚物非常适合用作内燃机的机油添加剂，特别是在工作温度基本恒定的情况下长时间工作的内燃机。
• LOW-ODOR, COLD-CURING (METH) ACRYLATE REACTION RESIN FOR FLOOR COATING, A FLOOR COATING CONTAINING THE REACTION RESIN, AND A PROCESS FOR THE PREPARATION OF THE FLOOR COATING
  申请人：——

  公开号：US20020002259A1

  公开（公告）日：2002-01-03

  The present invention relates to a low-odor, polymerizable, cold-curing (meth)acrylate composition for floor coatings exhibiting low health hazards during application and consisting of (A) 50-100 wt % a (meth)acrylate; (B) 0-2 parts by weight per 1 part by weight of (A) of a pre-polymer that dissolves or swells in (A); (C) 2-5 parts by weight per 100 parts by weight of (A+B) of at least one paraffin and/or wax; (D) a redox system, containing an accelerator and a peroxide catalyst or initiator in an amount that is adequate for cold-curing of Component A; and (E) a conventional additive.

  本发明涉及一种低气味、可聚合、冷固化(甲基)丙烯酸酯组合物，该组合物用于地坪涂料，在使用过程中对健康危害较小，其组成包括(A)50-100重量份的(甲基)丙烯酸酯；(B)每1重量份(A)中含0-2重量份可在(A)中溶解或溶胀的预聚物；(C) 每 100 份（A+B）重量中含 2-5 份（按重量计）至少一种石蜡和/或 蜡；(D) 氧化还原体系，其中含有促进剂和过氧化物催化剂或引发剂，其用量应 足以使 A 组分冷固化；以及 (E) 常规添加剂。
• Copolymers as dewaxing additives
  申请人：Scherer Markus

  公开号：US20050148749A1

  公开（公告）日：2005-07-07

  The invention relates to copolymers which are suitable for producing additives for solvent deparaffination of paraffin-containing mineral oil distillates and which consist of radically polymerized monomers of formulas A and B, wherein the radicals have the meaning cited in the description. The invention also relates to the use of said copolymers for the production of dewaxing additives.

  本发明涉及适用于生产含石蜡矿物油馏分溶剂脱蜡添加剂的共聚物，该共聚物由式 A 和 B 的辐射聚合单体组成，其中的自由基具有说明中引用的含义。本发明还涉及使用上述共聚物生产脱蜡添加剂。
• Lubricating grease with high water resistance
  申请人：Scherer Markus

  公开号：US20050245406A1

  公开（公告）日：2005-11-03

  The present invention relates to lubricating greases comprising at least one thickening agent and at least one lubricating oil, wherein the lubricating grease contains at least one polymeric structure improver that can be obtained by polymerization of monomer compositions, which are composed of a) 0 to 40 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of at least one (meth)acrylate of formula (I) in which R represents hydrogen or methyl, R 1 denotes a straight-chain or branched alkyl moiety having 1 to 5 carbon atoms, b) 40 to 99.99 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of at least one (meth)acrylate of formula (II) in which R represents hydrogen or methyl, R 2 denotes a straight-chain or branched alkyl moiety having 6 to 30 carbon atoms, c) 0.01 to 20 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of monomers containing acid groups or salts thereof, d) 0 to 59.99 wt %, relative to the weight of the monomer compositions for synthesis of the polymeric structure improvers, of comonomer.

  本发明涉及由至少一种稠化剂和至少一种润滑油组成的润滑脂，其中润滑脂含有至 少一种聚合物结构改良剂，该聚合物结构改良剂可通过单体组合物聚合获得，单体组合 物包括 a) 相对于用于合成聚合结构改进剂的单体组合物重量，0-40 wt % 的至少一种式 (I) 的（甲基）丙烯酸酯 其中 R 代表氢或甲基，R 1 表示具有 1 至 5 个碳原子的直链或支链烷基、 b) 相对于用于合成聚合物结构改进剂的单体组合物的重量，含有 40 至 99.99 wt % 的至少一种式（II）的（甲基）丙烯酸酯。 其中 R 代表氢或甲基，R 2 表示具有 6 至 30 个碳原子的直链或支链烷基、 c) 相对于用于合成聚合物结构改良剂的单体组合物重量，0.01-20 wt % 的含酸基团的单体或其盐， d) 相对于用于合成聚合物结构改良剂的单体组合物重量，0-59.99 wt % 的共聚单体。